Pb系简单钙钛矿氧化物PbMO<sub>3</sub>（M=3<i>d</i>过渡族金属）的高温高压制备及物性研究

于润泽

doi:10.11858/gywlxb.20230786

Pb系简单钙钛矿氧化物PbMO₃（M=3d过渡族金属）的高温高压制备及物性研究

doi: 10.11858/gywlxb.20230786

于润泽

北京高压科学研究中心, 北京　100193

基金项目: 国家自然科学基金（22020715）；国家重点研发计划（2023YFA1406000）

详细信息

作者简介:
于润泽（1980－），男，博士，研究员，主要从事量子功能材料的高压制备和物性调控研究. E-mail：runze.yu@hpstar.ac.cn

中图分类号: O521.2
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出版历程
- 收稿日期: 2023-11-08
- 修回日期: 2023-12-28
- 录用日期: 2024-01-02
- 刊出日期: 2024-02-05

High Pressure Synthesis and Physical Properties Investigation of Pb-Based Simple Perovskite Oxides PbMO₃ (M=3d transition metals)

YU Runze

Center for High Pressure Science and Technology Advanced Research, Beijing 100193, China

摘要

摘要: 系统总结了近十几年利用高压技术制备简单钙钛矿功能氧化物材料PbMO₃（M=3d过渡族金属）及其物性研究方面的进展，重点关注M元素变化过程中的晶体结构、电子结构、磁性和电输运性质的演化，以及高压调控下的结构相变、电荷转移和绝缘体金属化等行为，同时也对该领域中一些亟需解决的问题做了展望。
- Pb系钙钛矿 /
- 高压高温 /
- 3d过渡族金属氧化物
Abstract: In this paper, we reviewed the recent progress on the high-pressure synthesis of Pb-based simple perovskite compounds PbMO₃ (M=3d transition metals) and the investigation on their physical properties, mainly focusing on the M dependent crystal structure, electronic configuration, magnetism, transport properties, pressure induced structure phase transition, charge transfer and insulator to metal transitions. We also gave a comment on the unresolve problems in this system.
- Pb-based perovskite /
- high pressure high temperature /
- 3d transition metal oxides

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图 1 钙钛矿化合物的晶体结构

Figure 1. Crystal structure of perovskite compound

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图 2 PbVO₃的晶体结构^[10–11]：(a)沿b方向；(b)沿c方向；(c) 直流电阻率-压力演化曲线

Figure 2. Crystal structure of PbVO₃^[10–11]: (a) along b axis; (b) along c axis; (c) DC resistivity-pressure evolution curves

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图 3 高压下PbCrO₃的巨幅体积收缩^[19]

Figure 3. Large volume collapse of PbCrO₃ under high pressure^[19]

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图 4 (a) PbCrO₃中Cr-L_2,3的吸收边，(b) PbCrO₃中Cr的X射线吸收谱^[21]

Figure 4. (a) Cr- L_2,3 edge in PbCrO₃; (b) X-ray absorption spectra of Cr in PbCrO₃^[21]

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图 5 PbCrO₃中高分辨X射线吸收谱的Pb-L₃吸收边^[24]

Figure 5. Pb-L₃ edge of high-resolution X-ray absorption spectra in PbCrO₃^[24]

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图 6 PbCrO₃中高分辨X射线吸收谱的Pb-L₃吸收边随压力的演化^[24]

Figure 6. Pressure dependent Pb-L₃ edge of X-ray absorption spectra in PbCrO₃^[24]

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图 7 PbMnO₃的(a)同步辐射X射线粉末衍射谱图和(b)二次谐波光谱^[32]

Figure 7. (a) Synchrotron X-ray diffraction and (b) second harmonic generation of PbMnO₃^[32]

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图 8 PbMnO₃的X射线吸收谱：(a) Mn-L_2,3 吸收边，(b) Pb-L₃ 吸收边^[32]

Figure 8. X-ray absorption spectra in PbMnO₃: (a) Mn-L_2,3 edge, (b) Pb-L₃ edge^[32]

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图 9 PbMnO₃的(a)电阻率和热电势、(b)磁化率和Arrott曲线以及(c)比热容曲线^[32]

Figure 9. (a) Resistivity and thermoelectric power, (b) magnetization and Arrott plot curves and (c) specific heat curve of PbMnO₃^[32]

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图 10 PbFeO₃的 (a) 同步辐射X射线衍射谱、 (b)电子选区衍射图、(c)中子衍射谱以及(d)～(f)晶体结构和电荷序^[37]

Figure 10. (a) Synchrotron X-ray diffraction pattern, (b) selected electron diffraction, (c) neutron diffraction,(d)−(f) crystal structure and charge order of PbFeO₃^[37]

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图 11 PbFeO₃的(a)磁化率曲线、(b)磁滞回线、(c)～(d)温度诱导的自旋重排^[37]

Figure 11. (a) Magnetic susceptibility, (b) isothermal magnetization loops, (c)−(d) temperature induced spin reorientation of PbFeO₃^[37]

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图 12 PbCoO₃的(a)晶体结构、(b)磁化率和比定压热容（c_p）^[38]

Figure 12. (a) Crystal structure, (b) magnetic susceptibility and constant pressure specific heat capacity (c_p) of PbCoO₃^[38]

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图 13 (a) PbCoO₃ 中自旋和价态随压力的演化，(b) PbCoO₃ 的压力温度相图^[38]

Figure 13. (a) Schematic view of the origin of pressure induced spin state transition and charge transfer in PbCoO₃;(b) pressure and temperature dependent phase diagram of PbCoO₃^[38]

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图 14 PbNiO₃的晶体结构及其温度诱导的结构相变^[40]

Figure 14. Crystal structure and temperature inducedstructure phase transition of PbNiO₃^[40]

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图 15 PbMO₃ 系列钙钛矿材料的晶体结构和电子态的演化示意图

Figure 15. Schematic diagram of crystal and electronic configuration of PbMO₃ series compounds

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