快速压致凝固法制备块体亚稳材料的研究进展

刘秀茹; 王明友; 张豆豆; 张晨然; 何竹; 陈丽英; 沈如; 洪时明

doi:10.11858/gywlxb.2014.04.001

快速压致凝固法制备块体亚稳材料的研究进展

doi: 10.11858/gywlxb.2014.04.001

1.
西南交通大学物理科学与技术学院，材料先进技术教育部重点实验室，四川成都 610031
2.
西南交通大学分析测试中心，四川成都 610031

基金项目: 国家自然科学基金(11004163, 10774123);中央高校基础科研业务费(SWJTU12CX083，2682014ZT31)

详细信息

作者简介:
刘秀茹(1981-), 女, 博士, 副教授, 主要从事高压下亚稳材料的制备及物性研究.E-mail:xrliu@swjtu.edu.cn

通讯作者:
洪时明(1947-), 男, 博士, 教授, 主要从事高压物理及超硬材料研究.E-mail:smhong2@163.com

中图分类号: O521.3;O521.2
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出版历程
- 收稿日期: 2012-06-28
- 修回日期: 2012-09-20

Progress in Preparation of Bulk Metastable Materials by Rapid Compression-Induced Solidification

1.
School of Physical Science and Technology, Key Laboratory of Advanced Technologies of Materials, Ministry of Education, Southwest Jiaotong University, Chengdu 610031, China
2.
Analysis and Test Center, Southwest Jiaotong University, Chengdu 610031, China

摘要

摘要: 综述了快速增压使熔体凝固以获取非晶等亚稳相的方法和研究进展。介绍了自行研制的快速增压装置，展示了制备单质硫的大块非晶材料、单质硒的块体密实纳米材料、两种镧系基合金玻璃的块体材料，以及聚对苯二甲酸乙二醇酯(PET)、聚醚醚酮(PEEK)、等规聚丙烯(iPP)大块高分子亚稳材料的实验结果，证明了快速压致凝固法是制备块体亚稳材料的一种普遍可行的方法。最近的实验结果表明：快速压致凝固法获得的块体亚稳材料尺寸不受热传导率的限制；在快速压致凝固过程中，存在形成亚稳相的临界压力和临界增压速率两个限制条件。
- 压致凝固 /
- 快速增压 /
- 大块非晶材料 /
- 临界增压速率
Abstract: The method of preparing metastable materials (e.g.amorphous materials) by rapid compression-induced solidification and related research progress are reviewed in this paper.The authors prepared successfully bulk amorphous polymer PET (ethylene terephthalate), amorphous polymer PEEK (polyetheretherketone), mesomorphic phase of polymer iPP (isotactic polypropylene), amorphous sulfur, nanophase selenium, and two metallic glass La₆₈Al₁₀Cu₂₀Co₂ and Nd₆₀Cu₂₀Ni₁₀Al₁₀ using a rapid compression apparatus.These results indicate that the rapid compression is an effective method to prepare bulk metastable materials of many substances.It has been clearly demonstrated by recent experimental results that the size of metastable materials prepared by this method is not restricted by thermal conductivity, and furthermore it has been found that there exist a critical pressure and a critical compression rate of obtaining metastable phase during the rapid compression-induced solidification.
- pressure-induced solidification /
- rapid compression /
- bulk amorphous materials /
- critical compression rate

HTML全文

图 1 制取非晶材料的几种基本途径示意图

Figure 1. Schematic of several preparation methods of amorphous materials

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图 2 快速增压装置示意图^[18]

Figure 2. Schematic of the rapid compression apparatus^[18]

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图 3 典型的压力信号^[18]

Figure 3. Typical pressure record^[18]

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图 4(a) 活塞圆筒方式的样品组装

Figure 4(a). Sample assembly in the

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图 4(b) 平面对顶方式的样品组装

Figure 4(b). Sample assembly in the

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图 5 快速压致凝固法制备的大块非晶硫实物图(非晶硫显示出较高弹性)^[36]

Figure 5. Pictures of bulk amorphous sulfur prepared by rapid compression (It shows the amorphous sulfur possesses good elasticity)^[36]

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图 6 快速压致凝固法制备的纯非晶硫和摩尔分数为1%的碘掺杂非晶硫在常温常压下的一维WAXS谱(拍摄时间间隔为10 min)^[41]

Figure 6. WAXS patterns of pure amorphous sulfur and amorphous sulfur with 1% (mole fraction) I₂ additive prepared by rapid compression, which is taken at room temperature and atmosphere pressure with time interval of 10 min^[41]

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图 7 急冷法和快速压致凝固法制备的块体PEEK的剖面XRD谱^[33]

Figure 7. XRD patterns of PEEK samples prepared by rapid quenching and rapid compression taken along the longitudinal section^[33]

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图 8 473 K下以不同增压速率将iPP熔体压至1.5 GPa后回收样品的XRD谱

Figure 8. XRD patterns of iPP samples compressed to 1.5 GPa from melt under different compression rates at 473 K

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