金刚石对顶砧原位电导率测量系统

李明; 杨洁; 杨伍明; 王会新; 李立新; 高春晓

doi:10.11858/gywlxb.2012.01.004

金刚石对顶砧原位电导率测量系统

doi: 10.11858/gywlxb.2012.01.004

李明^1,2, ,,
杨洁³,
杨伍明¹,
王会新¹,
李立新¹,
高春晓²

1.
河南理工大学物理化学学院，河南焦作 454000；
2.
吉林大学超硬材料国家重点实验室，吉林长春 130012；
3.
空军航空大学基础部，吉林长春 130012

详细信息

通讯作者:
李明 E-mail:mli7901@yahoo.com.cn

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出版历程
- 收稿日期: 2010-07-07
- 修回日期: 2011-01-06
- 发布日期: 2012-02-15

An in Situ Electrical Conductivity Measurement System in Diamond Anvil Cell

1.
Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo 454000, China;
2.
National Laboratory of Superhard Materials, Jilin University, Changchun 130012, China;
3.
Fundamental Department, Aviation University of Air Force, Changchun 130012, China

摘要

摘要: 在金刚石对顶砧中进行原位高温高压电阻测量时，由于受到绝热层的限制，从而达不到理想的温度条件。采用普通的粉末绝热材料，会给电极的引入造成很大困难，而且不规则的电阻丝使电阻测量很难精确量化。利用溅射镀膜方法，在对顶砧的砧面上镀氧化铝膜作绝热层，溅射的金属钼膜作电极材料，成功地完成了高温高压条件下原位电阻的测量。利用此装置，测量了铁镁硅酸盐(Mg0.875,Fe0.125)2SiO4在高温高压环境下（31~35 GPa，1 500~3 400 K）的电导率，得到了样品的导电粒子激活能，发现其激活能随着压强的升高而增大，与低压低温（小于15 GPa，低于1 200 K）条件相比，其激活体积和激活能都明显减小。
- 金刚石对顶砧 /
- 高温高压 /
- 电导率 /
- 激活能
Abstract: In situ resistance measurement in a diamond anvil cell under high pressure and high temperature will be restricted by the thermal insulation. If the ordinary powder heat insulating material is used, it is difficult to introduce the electrode and measure resistance accurately. Here the in situ resistance measurement under high pressure and high temperature is performed successfully using a sputtered alumina film coated onto the surface of the top anvil plate as an insulation layer and a sputtered molybdenum film used as an electrode. With this device, the electrical conductivity of iron magnesium silicate [(Mg0.875,Fe0.125)2SiO4] under 31-35 GPa and 1 500-3 400 K is obtained. It is found that the activation energy increases with pressure, and the activation volume and activation energy are significantly reduced compared to that under the pressure and temperature lower than 15 GPa and 1 200 K.
- diamond anvil cell /
- high temperature and high pressure /
- electrical conductivity /
- activation energy

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参考文献(21)

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