The Research on Dissolvability and Phase Transition of Gypsum at High Pressure and Ambient Temperature
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摘要: 研究常温下200~1 100 MPa压力范围内石膏的Raman光谱,原位观测了随压力升高,石膏在水中的溶解现象,其过程中伴随着石膏的相变。结果表明:压力小于407 MPa时,石膏的形态无明显变化;随着压力的升高,石膏开始溶解,溶解至一定程度,石膏发生了向半水石膏转化的相变;相变完成后,半水石膏继续溶解至消失。石膏这一溶解相变过程表明在地球内部与压力相应的深部区域内,也可能会发生矿物的溶解相变。Abstract: The Raman spectra of gypsum during the pressure of 200~1 100 MPa is studied at ambient temperature, and the dissolvability and phase transition of gypsum are observed. It shows that gypsum is stable at the pressure less than 407 MPa; and then gypsum begins to dissolve with the increasing pressure. Gypsum stops dissolving and phase transition happens (gypsum-bassanite) to some degree. After phase transition, bassanite disappears with the rising pressure. It applies that geological disasters will happen because of dissolvability and phase transition of minerals in the inner of earth.
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Key words:
- high pressure /
- gypsum /
- dissolvability /
- phase transition
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Andri S. Dissolution of Primary Minerals of Basalt in Natural Waters: Ⅰ Calculation of Mineral Solubility from 0 ℃ to 350 ℃ [J]. Chemical Geology, 2001, 172: 225-250. Carrier H, Ye S Y, Vanderbeken I, et al. Salt Solubility under High Pressure and High Temperature [J]. High Temp-High Press, 1998, 30(6): 629-634. Liu D W, Kang Y L. Laboratory Investigation of Water Sensitivity of Carbonate Reservoirs and Discussion of Its Mechanism [J]. Natural Gas Industry, 2007, 27(2): 3-36. (in Chinese) 刘大伟, 康毅力. 碳酸盐岩储层水敏性实验评价及机理探讨 [J]. 天然气工程, 2007, 27(2): 3-36. Wu M, Wu L. Experiment of Controlling the Secondary Precipitation in Acid Gypsum-Containing Formation [J]. Drilling Production Technology, 2004, 27(3): 90-93. (in Chinese) 吴敏, 吴林. 控制酸化含石膏地层中的二次沉淀实验 [J]. 钻采工艺, 2004, 27(3): 90-93. Li W D, Wang W B. Problems Worthy of Consideration on the Study of Mesozoic Volcanic-Intrusive in Middle-Lower Yangtze Area [J]. Volcanology Mineral Resources, 1995, 16(2): 1-20. (in Chinese) 李文达, 王文斌. 长江中下游火山-侵入杂岩研究中值得探讨的几个问题(一) [J]. 火山地质与矿产, 1995, 16(2): 1-20. Cole W F, Lancucki C J. A Refinement of the Crystal Structure of Gypsum CaSO42H2O [J]. Acta Crystallogphy, 1974, 30: 921-929. Sherilyn C, Williams S, Josef P. Initiation and Growth of Gypsum Structures in the Zechstein Basin [J]. J Struct Geol, 1997, 19(7): 897-907. Winkler B, Hennion B. Low Temperature Dynamics of Molecular H2O in Bassanite, Gypsum and Investigated by High Resolution Incoherent Inelastic Neutron Scattering [J]. Phys Chem Miner, 1994, 21: 539. Zhao J, Zheng H F. Research on Raman Spectra of Calcite at Pressure of 0. 1~800 MPa [J]. Chinese Journal of High Pressure Physics, 2003, 17(3): 226-229. (in Chinese) 赵金, 郑海飞. 0. 1~800 MPa压力下方解石Raman拉曼的实验研究 [J]. 高压物理学报, 2003, 17(3): 226-229. Chen J Y, Zheng H F, Zeng Y S, et al. In-Situ Raman Spectroscopic Study of Fluid at High Temperature in Synthetic Inclusion [J]. Spectroscopy and Spectral Analysis, 2003, 23: 726-729. (in Chinese) 陈晋阳, 郑海飞, 曾贻善, 等. 以合成包裹体为腔体进行高温下流体的拉曼光谱原位分析 [J]. 光谱学与光谱分析, 2003, 23: 726-729. Yang Y Y, Zheng H F. Research on the Raman Spectra of Gypsum at Pressure of 100~800 MPa and Room Temperature [J]. Chinese Journal of High Pressure Physics, 2006, 20(1): 25-28. (in Chinese) 杨玉萍, 郑海飞. 常温和100~800 MPa下石膏的拉曼光谱研究 [J]. 高压物理学报, 2006, 20(1): 25-28. Couty R, Velde B, Besson J M. Raman Spectra of Gypsum under Pressure [J]. Phys Chem Miner, 1983, 10: 89-93. Knittle E, Phillips W, Williams Q. An Infrared and Raman Spectroscopic Study of Gypsum at High Pressures [J]. Phys Chem Miner, 2001, 28: 630-634. Sarma L P, Prasad P S R, Ravikumar N. Raman Spectroscopic Study of Phase Transitions in Natural Gypsum [J]. Raman Spectrosc, 1998, 29: 851-856. Zhou X Z, Zheng H F, Sun Q. In-Situ Raman Spectroscopic Study of Phase Transition at High Temperature and High Pressure [J]. Acta Petrologic Sinica, 2006, 22(12): 3047-2051. (in Chinese) 周兴志, 郑海飞, 孙樯. 高温高压下石膏脱水相变的原位拉曼光谱研究 [J]. 岩石学报, 2006, 22(12): 3047-3051. Schmidt C, Ziemann M A. In-Situ Raman Spectroscopy of Quartz: A Pressure Sensor for Hydrothermal Diamond-Anvil Cell Experiments at Elevated Temperatures [J]. Am Mineral, 2000, 85: 1725-1734. Zheng H F, Sun Q, Zhao J, et al. Comment on the Pressure Gauge for the Experiments at High Temperature and High Pressure with DAC [J]. Chinese Journal of High Pressure Physics, 2004, 18(1): 78-82. (in Chinese) 郑海飞, 孙樯, 赵金, 等. 金刚石压腔高温高压实验的压力标定方法及其现状 [J]. 高压物理学报, 2004, 18(1): 78-82.
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