新型含能富勒烯衍生物的合成研究

金波; 彭汝芳; 舒远杰; 钟发春; 楚士晋

doi:10.11858/gywlxb.2006.02.019

新型含能富勒烯衍生物的合成研究

doi: 10.11858/gywlxb.2006.02.019

1.
西南科技大学材料科学与工程学院，四川绵阳 621010；
2.
中国工程物理研究院化工材料研究所，四川绵阳 621900

详细信息

通讯作者:
彭汝芳

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出版历程
- 收稿日期: 2005-08-10
- 修回日期: 2005-10-20
- 发布日期: 2006-06-05

Study on the Synthesis of New Energetic Fullerene Derivative

1.
School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, China;
2.
Institute of Chemical Materials, CAEP, Mianyang 621900, China

More Information

Corresponding author: PENG Ru-Fang

摘要

摘要: 利用N-甲基甘氨酸、2，4-二硝基苯甲醛和C60反应，合成分离出了含有两个硝基的新型富勒烯吡咯烷衍生物1，并对其工艺条件进行了研究，探讨了反应物剂量比、温度和时间对产物1产率的影响，得到了合成产物1的最佳工艺条件：反应物剂量比为1∶2∶6、温度为95 ℃、反应时间为40 h，此时产物1产率可达到65.8%（以消耗的C60计）。同时用1H NMR、FT-IR、MS、UV-Vis等光谱手段确定了产物1的分子结构。
- N-甲基甘氨酸 /
- 2 /
- 4-二硝基苯甲醛 /
- C60 /
- 含能富勒烯 /
- 合成工艺
Abstract: A new fullerene derivative 1 which contains energy-producing groups was prepared by the Prato reaction, and the reaction conditions affecting the yield of product 1 were investigated. The optimized reaction conditions which afforded 65.8% (based on consumed C60) of product 1 are: molar ratio of C60, 2, 4-dinitrobenzaldehyde and N-methylglycine 1∶2∶6, reaction temperature 95 ℃, reaction time 40 h. The structure of product 1 was characterized by UV-vis, FT-IR, 1H NMR and MS. Further study on the property and application of 1 is under way.
- N-methylglycine /
- 2 /
- 4-dinitrobenzaldehyde /
- C60 /
- energetic fullerene /
- synthetic technology

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参考文献(18)

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