Effects of Graphitization on the Synthesis of Ultrafine Diamond by Explosive Detonation
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摘要: 金刚石的石墨化对于炸药爆轰过程中金刚石的产出率有重要的影响。对碳相图进行了讨论,提出采用金刚石-石墨的动力学平衡线来评价炸药爆轰过程中金刚石的石墨化。通过数值模拟,对炸药爆轰过程中金刚石的石墨化进行了分析和讨论。Abstract: Graphitization plays an important role in the synthesis of Ultrafine Diamond (UFD) during explosive detonation. Carbon phase diagram was studied and a diamond-graphite dynamic equilibrium line is introduced to study the effects of graphitization. The effects of graphitization under different charge conditions and preserving conditions were investigated numerically.
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Key words:
- graphitization /
- ultrafine diamond /
- detonation /
- carbon phase diagram
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Fedoseev D V, Bukhovets V L, Vnukov S P, et al. Surface Graphitization of Diamond at High Temperatures [J]. Phys Chem Mech Surfaces, 1989, 5(11): 131-134. Balaban A T, Klein D J. Local Interconversions between Graphite and Diamond Structures [J]. Carbon, 1997, 35(2): 247-251. 陈鹏万. 爆轰合成超微金刚石的机理及特性研究 [D]. 北京: 北京理工大学, 1999. Kuznetsov V L, Chuvilin A L, Moroz E M, et al. Effect of Explosion Conditions on the Structure of Detonation Soots: Ultradisperse Diamond and Onion Carbon [J]. Carbon, 1994, 32(5): 873-882. Vereschagin A L, Sakovich G V, Komarov V F, et al. Properties of Ultrafine Diamond Clusters from Detonation Synthesis [J]. Diamond and Related Materials, 1993, (3): 160. 袁公昱. 人造金刚石合成与金刚石工具制造 [M]. 长沙: 中南工业大学出版社, 1992. Gustufson P. An Evaluation of the Thermodynamic Properties and the p, T Phase Diagram of Carbon [J]. Carbon, 1986, 24(2): 169-176. Слободской В Я, Соболев В В. К Вопросу о Метаставилъно Й Кристаллизацииц Алмаза [J]. Химпческая Физика, 1989, 8(8): 1137-1141. 邵丙璜, 周之洪, 汪一通, 等. 爆炸法人造金刚石 [J]. 爆炸与冲击, 1986, 6(3): 198-207. 邵丙璜, 汪金通. 强击波作用下石墨转变金刚石的相变动力学 [J]. 物理, 1978, 8(3): 205-211. Titov V M, Anisichkin V F, Maikov I Y, et al. Synthesis of Ultrafine Diamonds in Detonation Waves [A]. The Ninth Symposium(International) on Detonation [C]. Oregan, 1989: 407.
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