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摘要: 通过各种材料的试验和压机设备因素的测定,总结了金刚石生长过程的特性:金刚石晶体是在石墨(G)-触媒(Me)界面上生长;因电阻R(G)R(Me)、温度T(G)T(Me)以及与外界热交换等原因,使合成腔内产生压力、温度梯度,成为金刚石生长之驱动力。梯度过大过小对金刚石生长均不利;金刚石晶体在G-Me界面两侧是非对称性生长;每个晶粒表面有一特殊结构约20 m左右厚的金属薄膜,它起到运载碳源和催化的双重作用。要合成粗粒高强金刚石,需要有一个稳定的合成体系。本文分析了该体系状态的性质及稳定的必要性与稳定的具体方法。Abstract: After studying various material behavior in the diamond synthesis processes and by measuring the factors in the HP/HT apparatus, we summarized the characteristics of diamond growth as follows: diamond grows on the graphite (G)-metal catalyst (Me) material interface. Since the resistance R(G)R(Me), temperature T(G)T(Me) and the heat exchange with outside, et al., the pressure and temperature gradients thus created in the cell will become the driving force of diamond growth. Too large or too small a driving force will be harmful to diamond growth. On the surface of each diamond crystal grain, there is a thin metallic layer of thickness about 15~20 m. This metallic thin film can both act as the carbon carrier as well as the catalyst. The growth of a coarse grain of high-strength diamond requires a stable synthesis system. The paper analyzed the property of such a system and proposed a way to establish the system.
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Key words:
- diamond /
- growth characteristic /
- stable system
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孙江, 等. 钢铁研究总院学报, 1985, 5(2): 231. 神田久生. 第21回高压讨论会讲演要旨集, 1980. 亓曾笃. 高压物理学报, 1990, 4(3): 204.
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