二级6-8型静高压装置厘米级腔体的设计原理与实验研究

何飞; 贺端威; 马迎功; 晏小智; 刘方明; 王永坤; 刘进; 寇自力; 彭放

doi:10.11858/gywlxb.2015.03.001

二级6-8型静高压装置厘米级腔体的设计原理与实验研究

doi: 10.11858/gywlxb.2015.03.001

何飞^1,,
贺端威^{1, 2,*, ,},
马迎功¹,
晏小智¹,
刘方明¹,
王永坤¹,
刘进¹,
寇自力¹,
彭放¹

1.
四川大学原子与分子物理研究所，四川成都 610065
2.
高能量密度物理教育部重点实验室，四川成都 610065

基金项目: 国家自然科学基金(51472171，11427810);国家重点基础研究发展计划(973项目)(2011CB808200)

详细信息

作者简介:
何飞：何飞(1989-), 男, 硕士, 主要从事大腔体静高压装置、超硬材料合成和高压材料物性究.E-mail:420263152@qq.com

通讯作者:
贺端威(1969—), 男，博士，教授，主要从事高压科学与技术、超硬材料及纳米材料的研究.E-mail: duanweihe@scu.edu.cn

中图分类号: O521.3
计量
- 文章访问数: 6681
- HTML全文浏览量: 2120
- PDF下载量: 267
出版历程
- 收稿日期: 2015-03-18
- 修回日期: 2015-03-27

Design Principles and Experimental Study of Centimeter-Scale Sample Chamber for Two-Stage 6-8 Type Static High Pressure Apparatus

1.
Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China
2.
Key Laboratory of High Energy Density Physics and Technology (Ministry of Education), Chengdu 610065, China

摘要

摘要: 利用大腔体静高压装置的实验数据，提出了“极限压缩体积比”的概念以及腔体与组装设计的一般性原理。通过对极限压缩体积比的分析，设计出了样品腔体达到厘米级的36/20(正八面体传压介质边长为36 mm/末级压砧正三角形截角边长为20 mm)组装。采用原位电阻观测Bi(Ⅲ-Ⅴ, 7.7 GPa)，ZnTe(Ⅰ-Ⅱ, 5 GPa; Ⅱ-Ⅲ, 8.9~9.5 GPa; 半导体-金属, 11.5~13.0 GPa)和ZnS(半导体-金属, 15.6 GPa)在高压下相变的方法, 标定了36/20组装的腔体压力。实验结果表明所设计样品腔的尺寸大于10 mm，压力可以达到15 GPa以上。本工作使得基于国产6×2 500 t(吨)铰链式六面顶压机的二级6-8型静高压装置在高压实验研究中具有更加广阔的应用前景。
- 大腔体静高压装置 /
- 压力标定 /
- 二级增压装置 /
- 六面顶压机
Abstract: By analyzing experimental data, we put forward the concept of the limit compression volume ratio and the general design principles of centimeter magnitude sample chamber for two-stage 6-8 type static high pressure apparatus.Based on the limit compression volume ratio, we designed an assembly of 36/20 (Octahedral edge-length 36 mm/anvil truncation edge-length 20 mm) with high pressure generating efficiency.Pressure calibration at room temperature for the 36/20 assembly was performed using the phase transitions of Bi (Ⅲ-Ⅴ, 7.7 GPa), ZnTe (Ⅰ-Ⅱ, 5 GPa; Ⅱ-Ⅲ, 8.9-9.5 GPa; semiconductor-metal, 11.5-13.0 GPa)and ZnS (semiconductor-metal, 15.6 GPa).The experimental results show that the pressure of sample chamber exceeds 15 GPa and the sample diameter reaches 1 cm.The improvements of two-stage 6-8 type static high pressure apparatus have great potential applications in high-pressure experimental research and industrial production.
- high pressure apparatus /
- pressure calibration /
- two-stage pressure cell /
- cubic press

HTML全文

图 1 八面体传压介质被压缩的示意图

Figure 1. Diagram of pressure medium in the compression process

下载: 全尺寸图片幻灯片

图 2 组装极限压缩体积比与八面体传压介质边长的关系

Figure 2. Relationship between the limit compression volume ratio of assembly and the octahedral edge-length

下载: 全尺寸图片幻灯片

图 3 组装极限压缩体积比与末级压砧截角边长的关系

Figure 3. Relationship between the limit compression volume ratio of assembly and the anvil truncation edge-length

下载: 全尺寸图片幻灯片

图 4 36/20组装的实验装配过程及多级加载示意图

Figure 4. Assembly processes of assembly 36/20 and schematic of multilevel load

下载: 全尺寸图片幻灯片

图 5(a) 标压物质ZnTe、ZnS的电路连接示意图

Figure 5(a). Circuit connection diagram of pressure calibration for ZnTe and ZnS

下载: 全尺寸图片幻灯片

图 5(b) 标压物质Bi的电路连接示意图

Figure 5(b). Circuit connection diagram of pressure calibration for Bi

下载: 全尺寸图片幻灯片

图 6 标压物质Bi的电阻值随外部加载的典型变化曲线

Figure 6. Resistance of Bi changing with applied load

下载: 全尺寸图片幻灯片

图 7 标压物质ZnTe的电阻值随外部加载的典型变化曲线

Figure 7. Resistance of ZnTe changing with applied load

下载: 全尺寸图片幻灯片

图 8 标压物质ZnS的电阻值随外部加载的典型变化曲线

Figure 8. Resistance of ZnS changing with applied load

下载: 全尺寸图片幻灯片

图 9 36/20组装的高压发生效率

Figure 9. Pressure generation efficiency of assembly 36/20 versus applied load

下载: 全尺寸图片幻灯片

图 10 实验前、后，14/8与36/20组装的传压介质对比图

Figure 10. Comparison of pressure medium between assembly 14/8 and assembly 36/20 before and after experiment

下载: 全尺寸图片幻灯片

表 1 常用组装的具体参数

Table 1. The specific parameters of assemblies

Octahedral edge- length/(mm)	Anvil truncation edge-length/(mm)	Limit compression volume ratio	Assembly	Reference
4.70	1.50	30.76	4.7/1.5	Kubo A, et al.(2000)^[18]
6.24	2.00	30.37	6.24/2	Shatskiy A, et al.(2011)^[19]
7.00	2.50	21.95	7/2.5	Akaogi M, et al.(1999)^[20]
8.00	3.00	18.96	8/3	Bertka C M, et al.(1997)^[21]
10.00	3.50	23.32	10/3.5	Stewart A J, et al.(2006)^[22]
10.00	4.00	15.63	10/4	Liebermann R C, et al.(1992)^[23]
14.00	6.00	12.70	14/6	Shatskiy A, et al.(2011)^[19]
14.00	7.00	8.00	14/7	Shatskiy A, et al.(2011)^[19]
16.00	7.00	11.94	16/7	Shatskiy A, et al.(2011)^[19]
18.00	8.00	11.39	18/8	Frost D J, et al.(2004)^[24]
18.00	9.00	8.00	18/9	Shatskiy A, et al.(2011)^[19]
25.00	15.00	4.63	25/15	Frost D J, et al.(2004)^[24]
38.00	22.00	5.15	38/22	Irifune T, (2010)^[25]

下载: 导出CSV

表 2 36/20组装的标压数据

Table 2. Data of pressure calibration for assembly 36/20

Pressure calibration material	Phase transformation	Chamber pressure/ (GPa)	Applied load/ (MN)
Bi	Ⅰ-Ⅱ	2.55	-
Bi	Ⅱ-Ⅲ	2.69	-
Bi	Ⅲ-Ⅴ	7.70	6.8
ZnTe	Ⅰ-Ⅱ	5.00	4.5
ZnTe	Ⅱ-Ⅲ	8.90-9.50	8.0
ZnTe	Semiconductor-metal	11.50-13.00	13.2
ZnS	Semiconductor-metal	15.6	19.0

下载: 导出CSV

参考文献(28)

[1]	Irifune T, Kurio A, Sakamoto S, et al. Materials: Ultrahard polycrystalline diamond from graphite[J]. Nature, 2003, 421(6923): 599-600. http://europepmc.org/abstract/med/12571587
[2]	Abelson P H. A potential phosphate crisis[J]. Science, 1999, 283: 2015. doi: 10.1126/science.283.5410.2015
[3]	Wigner E, Huntington H. On the possibility of a metallic modification of hydrogen[J]. J Chem Phys, 1935, 3(12): 764-770. doi: 10.1063/1.1749590
[4]	Ma Y, Eremets M, Oganov A R. Transparent dense sodium[J]. Nature, 2009, 458(7235): 182-185. doi: 10.1038/nature07786
[5]	Hemley R J, Soos Z G, Hanfland M, et al. Charge-transfer states in dense hydrogen charge-transfer states in dense hydrogen[J]. Nature, 1994, 369(6479): 384-387. doi: 10.1038/369384a0
[6]	Oganov A R, Ono S. Theoretical and experimental evidence for a post-perovskite phase of MgSiO₃ in Earth's D″ layer[J]. Nature, 2004, 430(6998): 445-448. doi: 10.1038/nature02701
[7]	Tian Y J, Xu B, Yu D L, et al. Ultrahard nanotwinned cubic boron nitride[J]. Nature, 2013, 493(7432): 385-388. doi: 10.1038/nature11728
[8]	Ma Y M, Eremets M, Oganov A R, et al. Transparent dense sodium[J]. Nature, 2009, 458(7235): 182-185. doi: 10.1038/nature07786
[9]	Irifune T, Sumiya H. Synthesis of nano-polycrystalline diamond(NPD)and its application to ultrahigh-pressure studies[J]. Rev High Press Sci Tech, 2011, 21(4): 278-284. doi: 10.4131/jshpreview.21.278
[10]	管俊伟, 贺端威, 王海阔, 等.力学结构及末级压砧硬度对八面体压腔高压发生效率的影响[J].物理学报, 2012, 61(10): 100701. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wlxb201210014 Guan J W, He D W, Wang H K, et al. Influence of mechanical configuration and hardness of last stage anvil on high pressure producing efficiency for octahedral cell[J]. Acta Phys Sinica, 2012, 61(10): 100701. (in Chinese) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wlxb201210014
[11]	郭滇生, 徐祖全, 陆振勤, 等.我国超硬材料六面顶液压机在国内外的应用现状及优势[J].超硬材料工程, 2008, 20(6): 33-37. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zbkj200806009 Guo D S, Xu Z Q, Lu Z Q, et al. Application status at home and abroad and advantages of cubic hinge press for superhard abrasives[J]. Superhard Material Engineering, 2008, 20(6): 33-37. (in Chinese) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zbkj200806009
[12]	贺端威, 王福龙, 寇自力, 等.用于产生超高压的新型装置: 中国, 200710048839.2[P]. 2007-12-26. He D W, Wang F L, Kou Z L, et al. New device used to produce ultrahigh pressure: China, 200710048839.2[P]. 2007-12-26. (in Chinese)
[13]	Qin J Q, He D W, Wang J H, et al. Is rhenium diboride a superhard material?[J]. Adv Mater, 2008, 20(24): 4780-4783. doi: 10.1002/adma.200801471
[14]	Xu C, He D W, Wang H K, et al. Nano-polycrystalline diamond formation under ultra-high pressure[J]. Int J Refract Met Hard Mater, 2012, 36: 232-237. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=7e54f550fd86d110fdc49bd918e5a9a7
[15]	Chen M, Wang S M, Zhang J, et al. Synthesis of stoichiometric and bulk CrN through a solid-state ion-exchange reaction[J]. Chem A Eur J, 2012, 18(48): 15459-15463. doi: 10.1002/chem.201202197
[16]	Wang W D, He D W, Tang M J, et al. Superhard composites of cubic silicon nitride and diamond[J]. Diam Relat Mater, 2012, 27: 49-53. http://www.sciencedirect.com/science/article/pii/S0925963512001380
[17]	王福龙, 贺端威, 房雷鸣, 等.基于铰链式六面顶压机的二级6-8型大腔体静高压装置[J].物理学报, 2008, 57(9): 5429. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wlxb200809014 Wang F L, He D W, Fang L M, et al. Design and assembly of split-sphere high pressure apparatus based on the hinge-type cubic-anviln press[J]. Acta Phys Sinica, 2008, 57(9): 5429. (in Chinese) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wlxb200809014
[18]	Kubo A, Akaogi M. Post-garnet transitions in the system Mg₄Si₄O₁₂-Mg₃Al₂Si₃O₁₂ up to 28 GPa: Phase relations of garnet, ilmenite and perovskite[J]. Phys Earth Planet Inter, 2000, 121(1): 85-102. http://www.sciencedirect.com/science/article/pii/S003192010000162X
[19]	Shatskiy A, Katsura T, Litasov K D, et al. High pressure generation using scaled-up Kawai-cell[J]. Phys Earth Planet Inter, 2011, 189(1): 92-108. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=935498005acbeae29baa43dedc7922be
[20]	Akaogi M, Hamada Y, Suzuki T, et al. High pressure transitions in the system MgAl₂O₄-CaAl₂O₄: A new hexagonal aluminous phase with implication for the lower mantle[J]. Phys Earth Planet Inter, 1999, 115(1): 67-77. doi: 10.1016/S0031-9201(99)00076-X
[21]	Bertka C M, Fei Y M. Mineralogy of the Martian interior up to core-mantle boundary pressures[J]. J Geophys Res B, 1997, 102(B3): 5251-5264. doi: 10.1029/96JB03270
[22]	Stewart A J, Westrenen W V, Schmidt M W, et al. Effect of gasketing and assembly design: A novel 10/3.5 mm multi-anvil assembly reaching perovskite pressures[J]. High Pressure Res, 2006, 26: 293-299. doi: 10.1080/08957950600835237
[23]	Liebermann R C, Wang Y B. High-Pressure Research: Application to Earth and Planetary Sciences[M]. Washington: American Geophysical Union, 1992: 19.
[24]	Frost D J, Poe B T, Trønnes, R G, et al. A new large-volume multianvil system[J]. Phys Earth Planet Inter, 2004, 143: 507-514. http://www.sciencedirect.com/science/article/pii/S0031920104001359
[25]	Irifune T. SOSEKI laboratory and new developments in multianvil technology[R]. Wuhan: TANDEM Symposium on Deep Earth Mineralogy, 2010.
[26]	Ohtani A, Motobayashi M, Onodera A. Polymorphism of ZnTe at elevated pressure[J]. Phys Lett A, 1980, 75(5): 435-437. doi: 10.1016/0375-9601(80)90866-X
[27]	Ovsyannikov S V, Shchennikov V V. Phase transitions investigation in ZnTe by thermoelectric power measurements at high pressure[J]. Solid State Commun, 2004, 132(5): 333-336. doi: 10.1016/j.ssc.2004.07.062
[28]	王文丹, 贺端威, 王海阔, 等.二级6-8型大腔体装置的高压发生效率机理研究[J].物理学报, 2010, 59(5): 3107. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wlxb201005030 Wang W D, He D W, Wang H K, et al. Reaserch on pressure generation efficiency of 6-8 type multianvil high pressure apparatus[J]. Acta Phys Sinica, 2010, 59(5): 3107. (in Chinese) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wlxb201005030