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Volume 29 Issue 1
Apr 2015
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Chinese Journal of High Pressure Physics  > 2015  >  29(1): 59-62.
CHEN Xi-Ping, FANG Lei-Ming, SUN Guang-Ai, PENG Fang, CHEN Bo, HE Duan-Wei, LIU Jing. Preparation and Pressure-Induced Cubic-to-Orthorhombic Phase Transition in ZrW2O8[J]. Chinese Journal of High Pressure Physics, 2015, 29(1): 59-62. doi: 10.11858/gywlxb.2015.01.010
Citation: CHEN Xi-Ping, FANG Lei-Ming, SUN Guang-Ai, PENG Fang, CHEN Bo, HE Duan-Wei, LIU Jing. Preparation and Pressure-Induced Cubic-to-Orthorhombic Phase Transition in ZrW2O8[J]. Chinese Journal of High Pressure Physics, 2015, 29(1): 59-62. doi: 10.11858/gywlxb.2015.01.010
shu

Preparation and Pressure-Induced Cubic-to-Orthorhombic Phase Transition in ZrW2O8

doi: 10.11858/gywlxb.2015.01.010
  • 1.

    Institute of Nuclear and Chemistry, CAEP, Mianyang 621999, China

  • 2.

    Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610064, China

  • 3.

    Institute of High Energy Physics, Chinese Academy of Science, Beijing 100039, China

  • Received Date: 30 Jan 2013
  • Rev Recd Date: 17 Mar 2013
    Abstract
  • Negative thermal expansion (NTE) ZrW2O8 powders were prepared by solid-state reaction with ZrO2 and WO3 powders.In situ high-pressure X-ray diffraction measurements for powder ZrW2O8 were performed by using a diamond anvil cell (DAC) with synchrotron radiation facility.The result shows that powder ZrW2O8 is cubic phase with a little WO3.At about 0.27 GPa and room temperature, theα-ZrW2O8 phase transforms into a quenchable orthorhombic structure called the γ phase.Upon further compression, the γ phase becomes amorphous at the pressure of 3.81 GPa.The obtained bulk modulus of α-ZrW2O8 and γ-ZrW2O8 are (40.0±3.8)GPa and (37.0±3.0)GPa.

     

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    • References(14)
  • [1]
    Mary T A, Evans J S O, Vogt T, et al. Negative thermal expansion from 0.3 to 1 050 Kelvin in ZrW2O8[J]. Science, 1996, 272(5258): 90-92. doi: 10.1126/science.272.5258.90
    [2]
    Sun Z H, Song X Y, Yin F X, et al. Giant negative thermal expansion in ultrafine-grained Mn3(Cu1-xGex)N(x=0.5)bulk[J]. J Phys D: Appl Phys, 2009, 42(12): 122004. doi: 10.1088/0022-3727/42/12/122004
    [3]
    Mary T A, Evans J S O, Sleight A W, et al. Negative thermal expansion in Sc2(WO4)3[J]. Solid State Chem, 1998, 137(1): 148-160. doi: 10.1006/jssc.1998.7744
    [4]
    Evans J S O, Mary T A, Vogt T, et al. Negative Thermal expansion in ZrW2O8 and HfW2O8[J]. Chem Mater, 1996, 8(12): 2809-2823. doi: 10.1021/cm9602959
    [5]
    Kowach G R. Growth of single crystals of ZrW2O8[J]. J Crystal Growth, 2000, 212(1/2): 167-172. http://www.sciencedirect.com/science/article/pii/S0022024899008921
    [6]
    Isobe T, Kato Y, Mizutani M, et al. Pressureless sintering of negative thermal expansion ZrW2O8/Zr2WP2O12 composites[J]. Mater Lett, 2008, 62(23): 3913-3915. doi: 10.1016/j.matlet.2008.05.046
    [7]
    Forster P M, Sleight A W. Negative thermal expansion in Y2W3O8[J]. Int J Inorgan Mater, 1999, 1(2): 123-127. doi: 10.1016/S1466-6049(99)00021-5
    [8]
    Evans J S O, Hu Z, Jorgensen J D, et al. Compressibility, phase transitions, and oxygen migration in zirconium tungstate, ZrW2O8[J]. Science, 1997, 275(5296): 61-65. doi: 10.1126/science.275.5296.61
    [9]
    Mittal R, Chaplot S L. Lattice dynamical calculation of isotropic negative thermal expansion in ZrW2O8 over 0-1 050 K[J]. Phys Rev B, 1999, 60(10): 7234-7237. doi: 10.1103/PhysRevB.60.7234
    [10]
    Jorgensen J D, Hu Z, Teslic S, et al. Pressure-induced cubic-to-orthorhombic phase transition in ZrW2O8[J]. Phys Rev B, 1999, 59(1): 215-225. doi: 10.1103/PhysRevB.59.215
    [11]
    Perottoni C A, da Jornada J A H. Pressure-induced amorphization and negative thermal expansion in ZrW2O8[J]. Science, 1998, 280(5365): 886-889. doi: 10.1126/science.280.5365.886
    [12]
    Pantea C, Migliori A, Littlewood P B, et al. Pressure-induced elastic softening of monocrystalline zirconium tungstate at 300 K[J]. Phys Rev B, 2006, 73(21): 214118. doi: 10.1103/PhysRevB.73.214118
    [13]
    Drymiotis F R, Ledbetter H, Betts J B, et al. Monocrystal elastic constants of the negative-thermal-expansion compound zirconium tungstate(ZrW2O8)[J]. Phys Rev Lett, 2004, 93(2): 025502. doi: 10.1103/PhysRevLett.93.025502
    [14]
    Liu W, Li B S. Elasticity of amorphous zirconium tungstate at high pressure[J]. Appl Phys Lett, 2008, 93(19): 191904. doi: 10.1063/1.3023049
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