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LI Peng, LI Liang-Bin, HUANG Rui, CAI Bi-Hua, FAN Wu-Yi, LIU Fu-Sheng, ZHANG Qing-Fu, SHI Shang-Chun. Surface Modification of HDPE and PC under Shock Pressure[J]. Chinese Journal of High Pressure Physics, 1999, 13(4): 262-267 . doi: 10.11858/gywlxb.1999.04.004
Citation: LI Peng, LI Liang-Bin, HUANG Rui, CAI Bi-Hua, FAN Wu-Yi, LIU Fu-Sheng, ZHANG Qing-Fu, SHI Shang-Chun. Surface Modification of HDPE and PC under Shock Pressure[J]. Chinese Journal of High Pressure Physics, 1999, 13(4): 262-267 . doi: 10.11858/gywlxb.1999.04.004

Surface Modification of HDPE and PC under Shock Pressure

doi: 10.11858/gywlxb.1999.04.004
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  • Corresponding author: LI Peng
  • Received Date: 27 Nov 1998
  • Rev Recd Date: 01 Apr 1999
  • Issue Publish Date: 05 Dec 1999
  • The surface of HDPE and PC samples undergone transient shock pressure were investigated with ESCA and FT-IR, which show high oxygen/carbon ratio of 0.195∶1 and 0.266 ∶1 respectively, suggest that oxygen-containing groups are rich on the surface. The high pressure and temperature induced by shock are responsible for the chemical reaction directly. Large quantity of reactive sites and macromolecular radicals are formed while carbonization and oxydehydrogenation occurring. They then react with ambient oxygen on the spot, resulting in graft or substitution of the surface material.

     

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