Volume 38 Issue 1
Feb 2024
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SUN Hao, YE Pengda, LIU Yuwei, JIN Meiling, LI Xiang. High-Pressure Synthesis of Copper-Based Rare-Earth Perovskite La1–xNdxCuO3 (0≤x≤1)[J]. Chinese Journal of High Pressure Physics, 2024, 38(1): 010104. doi: 10.11858/gywlxb.20230784
Citation: SUN Hao, YE Pengda, LIU Yuwei, JIN Meiling, LI Xiang. High-Pressure Synthesis of Copper-Based Rare-Earth Perovskite La1–xNdxCuO3 (0≤x≤1)[J]. Chinese Journal of High Pressure Physics, 2024, 38(1): 010104. doi: 10.11858/gywlxb.20230784

High-Pressure Synthesis of Copper-Based Rare-Earth Perovskite La1–xNdxCuO3 (0≤x≤1)

doi: 10.11858/gywlxb.20230784
  • Received Date: 08 Nov 2023
  • Rev Recd Date: 30 Dec 2023
  • Accepted Date: 02 Jan 2024
  • Issue Publish Date: 05 Feb 2024
  • The copper-based rare-earth perovskites La1–xNdxCuO3(0≤x≤1) have been synthesized in the two-stage Walker-type high-pressure apparatus. The refined crystal structure results revealed that La1–xNdxCuO3 (0≤x≤0.4) adopts a rhombohedral structure with the space group $R\overline 3 c $. When 0.5≤x≤0.7, a mixed phase with both $R\overline 3 c $ rhombohedral and Pnma orthorhombic structures was observed in the system. With a further increase in Nd3+ doping, the system exhibits a single Pnma orthorhombic phase when x=0.8, 0.9 and 1. A comprehensive structural phase diagram of La1–xNdxCuO3 (0≤x≤1) was established in this study, providing a new material platform for investigating the magnetic properties, metal-insulator transitions, and other physical property evolutions in rare-earth 3d transition metal oxides.

     

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