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Volume 35 Issue 3
Jun 2021
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Chinese Journal of High Pressure Physics  > 2021  >  35(3): 035301.
CAO Xuewen, YANG Kairan, YANG Jian, TANG Guoxiang, BIAN Jiang. Experiment and Simulation of Carbon Dioxide Hydrate Formation Mechanism under High Pressure[J]. Chinese Journal of High Pressure Physics, 2021, 35(3): 035301. doi: 10.11858/gywlxb.20200632
Citation: CAO Xuewen, YANG Kairan, YANG Jian, TANG Guoxiang, BIAN Jiang. Experiment and Simulation of Carbon Dioxide Hydrate Formation Mechanism under High Pressure[J]. Chinese Journal of High Pressure Physics, 2021, 35(3): 035301. doi: 10.11858/gywlxb.20200632
shu

Experiment and Simulation of Carbon Dioxide Hydrate Formation Mechanism under High Pressure

doi: 10.11858/gywlxb.20200632

  • College of Pipeline and Civil Engineering, China University of Petroleum, Qingdao 266580, Shandong, China

  • Received Date: 04 Nov 2020
  • Rev Recd Date: 13 Nov 2020
  • Publish Date: 25 Dec 2020
    Abstract
  • The capturing and storage of green-house gas carbon dioxide are greatly significant to alleviation of green-house effect. The storage method producing carbon dioxide hydrate has advantages of high efficiency, large amount of storage, and easily transporting, etc. In order to provide suggestions for producing CO2 hydrate, experimental and modelling study of CO2 hydrate formation mechanism were initiated in this study. Hydrate formation thermodynamic model was established to give a prediction of temperature and pressure conditions for CO2 hydrate formation and made verification through the experimental data obtained by high-pressure constant reactor system. Hydrate formation kinetic model was built on the assumption that the chemical potential difference serves as the formation drive force. Compared with the experimental results, the model predicted results are agreed in tolerant discrepancy. Moreover, the pressure influence of reactor on CO2 hydrate formation rate was also analyzed. It is indicated that the escalation of pressure can stimulate the formation drive force under lower equilibrium temperature, prompting the gas-liquid mass transferring and production efficiency. Based on the change of electrical resistance ratio obtained from experimental record, CO2 hydrates firstly nucleate and agglomerate at top area of the reactor, additionally close to the wall.

     

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    • References(20)
  • [1]
    RODHE H. A comparison of the contribution of various gases to the greenhouse effect [J]. Science, 1990, 248(4960): 1217–1219. doi: 10.1126/science.248.4960.1217
    [2]
    BACHU S, BONIJOLY D, BRADSHAW J, et al. CO2 storage capacity estimation: methodology and gaps [J]. International Journal of Greenhouse Gas Control, 2007, 4: 430–443.
    [3]
    LIU Y, WANG P, YANG M, et al. CO2 sequestration in depleted methane hydrate sandy reservoirs [J]. Journal of Natural Gas Science Engineering, 2018, 49: 428–434. doi: 10.1016/j.jngse.2017.10.023
    [4]
    LI Q, FAN S, CHEN Q, et al. Experimental and process simulation of hydrate-based CO2 capture from biogas [J]. Journal of Natural Gas Science Engineering, 2019, 72: 103008. doi: 10.1016/j.jngse.2019.103008
    [5]
    SLOANJR E D, KOH C. Clathrate hydrates of natural gases [M]. CRC Press, 2007.
    [6]
    SONG Y, WANG S, JIANG L, et al. Hydrate phase equilibrium for CH4-CO2-H2O system in porous media [J]. The Canadian Journal of Chemical Engineering, 2016, 94(8): 1592–1598. doi: 10.1002/cjce.22529
    [7]
    王金宝, 郭绪强, 陈光进, 等. 二氧化碳置换法开发天然气水合物的实验研究 [J]. 高校化学工程学报, 2007, 21(4): 173–177.

    WANG J B, GUO X Q, CHEN G J, et al. Experimental research on methane recovery from natural gas hydrate by carbon dioxide replacement [J]. Journal of Chemical Engineering of Chinese Universities, 2007, 21(4): 173–177.
    [8]
    FEYZI V, MOHEBBI V. Experimental study and modeling of the kinetics of carbon-dioxide hydrate formation and dissociation: a mass transfer limited kinetic approach [J]. Journal of Natural Gas Science and Engineering, 2020, 77: 103273. doi: 10.1016/j.jngse.2020.103273
    [9]
    HERRI J M, BOUCHEMOUA A, KWATERSKI M, et al. Enhanced selectivity of the separation of CO2 from N2 during crystallization of semi-clathrates from quaternary ammonium solutions [J]. Oil & Gas Science and Technology, 2014, 69(5): 947–968.
    [10]
    ZHOU S, YAN H, SU D, et al. Investigation on the kinetics of carbon dioxide hydrate formation using flow loop testing [J]. Journal of Natural Gas Science Engineering, 2018, 49: 385–392. doi: 10.1016/j.jngse.2017.10.022
    [11]
    WAALS J H V D, PLATTEEUW J C. Clathrate solutions [M]. Advances in Chemical Physics. John Wiley Business Services Ltd, 2007.
    [12]
    PARRISH W R, PRAUSNITZ J M. Dissociation pressures of gas hydrates formed by gas mixtures [J]. Industrial & Engineering Chemistry Process Design and Development, 1972, 22(1): 26–35.
    [13]
    CHEN G J, GUO T M. Thermodynamic modeling of hydrate formation based on new concepts [J]. Fluid Phase Equilibrium, 1996, 122(1/2): 43–65.
    [14]
    CHEN G J, GUO T M. A new approach to gas hydrate modelling [J]. Chemical Engineering, 2000, 71(2): 145–151.
    [15]
    陈光进, 马庆兰, 郭天民. 气体水合物生成机理和热力学模型的建立 [J]. 化工学报, 2000, 21(5): 626–631. doi: 10.3321/j.issn:0438-1157.2000.05.010

    CHEN G J, MA Q L, GUO T M. A new mechanism for hydrate formation and development of thermodynamic model [J]. Journal of Chemical Industry and Engineering, 2000, 21(5): 626–631. doi: 10.3321/j.issn:0438-1157.2000.05.010
    [16]
    YIN Z, KHURANA M, TAN H K, et al. A review of gas hydrate growth kinetic models [J]. Chemical Engineering, 2018, 342: 9–29. doi: 10.1016/j.cej.2018.01.120
    [17]
    SKOVBORG P, RASMUSSEN P. A mass transport limited model for the growth of methane and ethane gas hydrates [J]. Chemical Engineering Science, 1994, 49(8): 1131–1143. doi: 10.1016/0009-2509(94)85085-2
    [18]
    MOHEBBI V, NADERIFAR A, BEHBAHANI R, et al. A mass transfer study of methane and ethane during hydrate formation [J]. Petroleum Science Technology, 2014, 32(12): 1418–1425. doi: 10.1080/10916466.2012.656872
    [19]
    MOHEBBI V, BEHBAHANI R M, NADERIFAR A. A new approach for modeling of multicomponent gas hydrate formation [J]. Korean Journal of Chemical Engineering, 2017, 34(3): 1–11.
    [20]
    李彦龙, 陈强, 吴能友, 等. 电阻率层析成像技术在岩芯尺度水合物可视化探测中的应用 [J]. 地质论评, 2020, 66(S1): 84–86.

    LI Y L, CHEN Q, WU N Y, et al. Core-scale application of electrical resistivity tomography technology on visual detection of natural gas hydrate [J]. Geological Review, 2020, 66(S1): 84–86.
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