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Volume 33 Issue 4
Jul 2019
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Chinese Journal of High Pressure Physics  > 2019  >  33(4): 043101.
LIU Yungui, LÜ Zhengxing, SONG Haipeng, WU Xiang. Fluorescence Mechanism of Diamond and the Significance in High Pressure Raman Spectrometry[J]. Chinese Journal of High Pressure Physics, 2019, 33(4): 043101. doi: 10.11858/gywlxb.20180689
Citation: LIU Yungui, LÜ Zhengxing, SONG Haipeng, WU Xiang. Fluorescence Mechanism of Diamond and the Significance in High Pressure Raman Spectrometry[J]. Chinese Journal of High Pressure Physics, 2019, 33(4): 043101. doi: 10.11858/gywlxb.20180689
shu

Fluorescence Mechanism of Diamond and the Significance in High Pressure Raman Spectrometry

doi: 10.11858/gywlxb.20180689
  • 1.

    College of Gems and Materials Technology, Hebei GEO University, Shijiazhuang 050031, China

  • 2.

    State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074, China

  • Received Date: 14 Nov 2018
  • Rev Recd Date: 05 Dec 2018
    Abstract
  • High pressure Raman scattering spectrometry which based on the diamond anvil cell technology plays an important role in the high pressure scientific research. The fluorescence of diamond anvil affects on the signal-to-noise ratio of Raman spectral for the sample in cell. The defect centers of 202 gem-grade diamonds have been confirmed by the photoluminescence spectra. The concentration of N3, H3 and NV0 defect centers controls the intensity of the zero-phonon line and the fluorescence emission spectrum, and it is positively correlated to the fluorescence intensity. While, the ratio of background intensity on the two sides of the diamond’s second-order Raman peak (about 2664 cm–1) has a negative correlation with the fluorescence intensity, thus it could be used to estimate the fluorescence intensity of diamond. In addition, the inhomogeneous of the concentration of defect centers is common in diamond, and it will provide more comprehensive information by multipoint analysis. The results will provide effective theoretical and practical basis for the selection of diamond anvil in high pressure Raman spectra measurement.

     

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