Synthesis of Hard Superconductive Ternary Transition Metal Carbide under High Pressure and High Temperature

GAO Hao'an; MA Shuailing; BAO Kuo; ZHU Pinwen; CUI Tian

doi:10.11858/gywlxb.20170633

Volume 32 Issue 2

Jan 2018

Turn off MathJax

Article Contents

Chinese Journal of High Pressure Physics > 2018 > 32(2): 023301.

GAO Hao'an, MA Shuailing, BAO Kuo, ZHU Pinwen, CUI Tian. Synthesis of Hard Superconductive Ternary Transition Metal Carbide under High Pressure and High Temperature[J]. Chinese Journal of High Pressure Physics, 2018, 32(2): 023301. doi: 10.11858/gywlxb.20170633

Citation:

GAO Hao'an, MA Shuailing, BAO Kuo, ZHU Pinwen, CUI Tian. Synthesis of Hard Superconductive Ternary Transition Metal Carbide under High Pressure and High Temperature[J]. Chinese Journal of High Pressure Physics, 2018, 32(2): 023301. doi: 10.11858/gywlxb.20170633

Citation:

PDF( 3087 KB)

Synthesis of Hard Superconductive Ternary Transition Metal Carbide under High Pressure and High Temperature

doi: 10.11858/gywlxb.20170633

GAO Hao'an^{1, 2
,},
MA Shuailing¹,
BAO Kuo^{1,*
,
,},
ZHU Pinwen¹,
CUI Tian¹

1.
State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun130012, China
2.
High School Attached to Northeast Normal University, Changchun130021, China

Received Date: 21 Aug 2017
Rev Recd Date: 03 Sep 2017

Abstract

Abstract

In the present work MoWC₂ was successfully fabricated under 5.0GPa/2000K with a holding time of 60min using, as the synthetic raw material, molybdenum, tungsten and graphite powder (whose purity are more than 99.8%).Then the physical properties of the synthesized samples were characterized using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, micro-hardness test, physical property measurement system and thermo gravimetric-differential thermal analyzer (TG-DTA).The results show that the MoWC₂ crystal thus synthesized has a hexagonal structure with a space group of P6-m2.It is highly crystalline with an average grain size of 1-4μm.Its convergence hardness value, oxidation temperature and the superconducting temperature are 15.3GPa, 450℃ and 6.8K, respectively.In addition, this MoWC₂ has a high hardness and oxidation resistance owing to its strong orbital hybridization.Furthermore, it is a superconducting material with a relatively high transition temperature since it has a higher density of states at the Fermi surface and Debye temperature, thereby making it a versatile material that is superconductive, highly heat-resistant, and superhard.
- high pressure and high temperature,
- transition metal carbide,
- superconductivity,
- Vickers hardness,
- oxidation resistance

FullText(HTML)

References(32)

References

[1]	包括, 马帅领, 徐春红, 等.过渡金属轻元素化合物高硬度多功能材料的设计[J].物理学报, 2017, 66(3):036104. BAO K, MA S L, XU C H, et al.Design of ultra-hard multifunctional transition metal compounds[J]. Acta Physica Sinica, 2017, 66(3):036104.
[2]	陶强. MoB₂和WB₃的高温高压合成及其结构和硬度性质研究[D]. 长春: 吉林大学, 2015: 27-40, 61-63. TAO Q. Exploring the structures and hardness of MoB₂ and WB₃ synthesized by high pressure and high temperature[D]. Changchun: Jilin University, 2015: 27-40, 61-63.
[3]	QI Q, LIU Y, WANG L J, et al.One new route to optimize the oxidation resistance of TiC/hastelloy (Ni-based alloy) composites applied for intermediate temperature solid oxide fuel cell interconnect by increasing graphite particle size[J]. Journal of Power Sources, 2017, 362:57-63. doi: 10.1016/j.jpowsour.2017.06.085
[4]	MA T, LI H, ZHENG X, et al.Ultrastrong boron frameworks in ZrB₁₂:a highway for electron conducting[J]. Advanced Materials, 2017, 29(3):1-6. https://www.researchgate.net/publication/320956356_Zirconium_Boride_as_a_High_Fluence_Saturable_Absorber_for_Q-Switched_Fiber_Lasers
[5]	ZHANG G T, GAO R, ZHAO Y R, et al.First-principles investigation on crystal structure and physical properties of HfB₄[J]. Journal of Alloys & Compounds, 2017, 723:802-810.
[6]	KAYHAN M, HILDEBRT E, FROTSCHER M, et al.Neutron diffraction and observation of superconductivity for tungsten borides, WB and W₂B₄[J]. Solid State Sciences, 2012, 14(11/12):1656-1659.
[7]	GASPAROV V, SHEIKIN I, OTANI S.Electron transport and superconducting properties of ZrB₁₂, and YB₆[J]. Physica C:Superconductivity & Its Applications, 2007, 460:623-625.
[8]	KAVITHA M, PRIYANGA G S, RAJESWARAPALANICHAMY R, et al.Structural stability, electronic, mechanical and superconducting properties of CrC and MoC[J]. Materials Chemistry & Physics, 2016, 169:71-81. https://www.sciencedirect.com/science/article/pii/S0254058415304582
[9]	HWANG T J, KIM D H.Variation of superconducting transition temperature by proximity effect in NbN/FeN bilayers[J]. Physica C:Superconductivity & Its Applications, 2017, 540(15):16-19. https://www.sciencedirect.com/science/article/pii/S0921453417301260
[10]	BOI F S, GUO J, XIANG G, et al.Cm-size free-standing self-organized buckypaper of bucky-onions filled with ferromagnetic Fe₃C[J]. RSC Advances, 2017, 7(2):845-850. doi: 10.1039/C6RA24983C
[11]	MA S L, BAO K, TAO Q, et al.Manganese mono-boride, an inexpensive room temperature ferromagnetic hard material[J]. Scientific Reports, 2017, 7:43759. doi: 10.1038/srep43759
[12]	ZHDANOVA O V, LYAKHOVA M B, PASTUSHENKOV Y G.Magnetic properties and domain structure of FeB single crystals[J]. Metal Science & Heat Treatment, 2013, 55(1/2):68-72. doi: 10.1007/s11041-013-9581-0.pdf
[13]	VAARMETS K, NERUT J, SEPP S, et al.Accelerated durability tests of molybdenum carbide derived carbon based Pt catalysts for PEMFC[J]. Journal of the Electrochemical Society, 2017, 164(4):338-346. doi: 10.1149/2.1021704jes
[14]	XU Y T, XIAO X, YE Z M, et al.Cage-confinement pyrolysis route to ultrasmall tungsten carbide nanoparticles for efficient electrocatalytic hydrogen evolution[J]. Journal of the American Chemical Society, 2017, 139(15):5285. doi: 10.1021/jacs.7b00165
[15]	MAKOTA O, WOLF J, TRACH Y, et al.Epoxidation of cyclooctene with hydroperoxy sultams catalyzed by molybdenum boride[J]. Applied Catalysis A:General, 2007, 323(5):174-180. https://www.sciencedirect.com/science/article/pii/S0926860X0700097X
[16]	SIMONENKO E P, IGNATOV N A, SIMONENKO N P, et al.Synthesis of highly dispersed super-refractory tantalum-zirconium carbide Ta₄ZrC₅, and tantalum-hafnium carbide Ta₄HfC₅, via sol-gel technology[J]. Russian Journal of Inorganic Chemistry, 2011, 56(11):1681-1687. doi: 10.1134/S0036023611110258
[17]	SCANLON M D, BIAN X, VRUBEL H, et al.Low-cost industrially available molybdenum boride and carbide as "platinum-like" catalysts for the hydrogen evolution reaction in biphasic liquid systems[J]. Physical Chemistry Chemical Physics, 2013, 15(8):2847-2857. doi: 10.1039/c2cp44522k
[18]	HUNT S T, NIMMANWUDIPONG T, ROMAN-LESHKOV Y.Engineering non-sintered, metal-terminated tungsten carbide nanoparticles for catalysis[J]. Angewandte Chemie, 2014, 53(20):5131-5136.
[19]	MOHAMMADI R, TURNER C L, XIE M, et al.Enhancing the hardness of superhard transition-metal borides: molybdenum-doped tungsten tetraboride[J]. Chemistry of Materials, 2016, 28(2):632-637. doi: 10.1021/acs.chemmater.5b04410
[20]	YEUNG M T, LEI J, MOHAMMADI R, et al.Superhard monoborides:hardness enhancement through alloying in W_1-x Ta_xB[J]. Advanced Materials, 2016, 28(32):6993-6998. doi: 10.1002/adma.201601187
[21]	EMAMIAN A, FARSHIDIANFAR M H, KHAJEPOUR A.Thermal monitoring of microstructure and carbide morphology in direct metal deposition of Fe-Ti-C metal matrix composites[J]. Journal of Alloys & Compounds, 2017, 710:20-28. https://www.sciencedirect.com/science/article/pii/S0925838817309994
[22]	HU Y F, JIA G, MA S L, et al.Hydrogen evolution reaction of γ-Mo_0.5W_0.5C achieved by high pressure high temperature synthesis[J]. Catalysts, 2016, 6(12):208-215. doi: 10.3390/catal6120208
[23]	崔田, 冯小康, 朱品文, 等. 氮化铬的高温高压制备方法: CN 106517111A[P]. 2017-03-22. CUI T, FENG X K, ZHU P W, et al. Preparation of chromium nitride at high temperature and high pressure: CN 106517111A[P]. 2017-03-22.
[24]	KURLOV A S, GUSEV A I.Density and particle size of cubic niobium carbide NbCy, nanocrystalline powders[J]. Physics of the Solid State, 2017, 59(1):184-190. doi: 10.1134/S106378341701019X
[25]	MA S L, BAO K, TAO Q, et al.An ultra-incompressible ternary transition metal carbide[J]. RSC Advances, 2014, 4(108):63544-63548. doi: 10.1039/C4RA13193B
[26]	KUMAR P, SINGH M, SHARMA R K, et al. Effect of plasma voltage on sulfurization of α-MoO₃ nanostructured thin films[C]//International Conference on Condensed Matter & Applied Physics. AIP Publishing, 2016: 2320-2325.
[27]	YANG Y A, MA Y, YAO J N, et al.Simulation of the sublimation process in the preparation of photochromic WO₃, film by laser microprobe mass spectrometry[J]. Journal of Non-Crystalline Solids, 2000, 272(1):71-74. doi: 10.1016/S0022-3093(00)00226-X
[28]	李峰.日本研制出新型超导材科——含硼金刚石薄膜[J].功能材料信息, 2004, 1(3):61. https://www.doc88.com/p-5425090739892.html LI F.Japan developed a new superconducting materials-boron-containing diamond film[J]. Functional Materials Information, 2004, 1(3):61. https://www.doc88.com/p-5425090739892.html
[29]	SHAKHOV F M, ABYZOV A M, KIDALOV S V, et al.Boron-doped diamond synthesized at high-pressure and high-temperature with metal catalyst[J]. Journal of Physics & Chemistry of Solids, 2016, 103:224-237. https://www.sciencedirect.com/science/article/pii/S0022369716308216
[30]	GOU H, DUBROVINSKAIA N, BYKOVA E, et al.Discovery of a superhard iron tetraboride superconductor[J]. Physical Review Letters, 2013, 111(15):157002. doi: 10.1103/PhysRevLett.111.157002
[31]	WANG S, ANTONIO D, YU X, et al.The hardest superconducting metal nitride[J]. Scientific Reports, 2015, 5:13733. doi: 10.1038/srep13733
[32]	PADUANI C.Electronic structure and Fermi surfaces of transition metal carbides with rocksalt structure[J]. Journal of Physics:Condensed Matter, 2008, 20(22):225014. doi: 10.1088/0953-8984/20/22/225014

Relative Articles

Supplements(0)

Cited By

Proportional views

Proportional views

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Figures(7)

Get Citation

PDF

XML

Article Metrics

Article views(7483) PDF downloads(256)

Synthesis of Hard Superconductive Ternary Transition Metal Carbide under High Pressure and High Temperature

doi: 10.11858/gywlxb.20170633

Abstract

References

Proportional views

Catalog

通讯作者: 陈斌, bchen63@163.com

Article Metrics

Proportional views

Related

Synthesis of Hard Superconductive Ternary Transition Metal Carbide under High Pressure and High Temperature

doi: 10.11858/gywlxb.20170633

Abstract

References

Proportional views

Catalog

通讯作者: 陈斌, bchen63@163.com

Article Metrics

Proportional views

Related

Export File

Citation

Format

Content