Effect of Ferrocene Precursor Mass on Gaseous Detonation Synthesisof Carbon Nanotubes

YANG Rui; LI Xiao-Jie; YAN Hong-Hao; KONG Ling-Jie

doi:10.11858/gywlxb.2017.04.006

Volume 31 Issue 4

Aug 2017

Turn off MathJax

Article Contents

Chinese Journal of High Pressure Physics > 2017 > 31(4): 389-395.

YANG Rui, LI Xiao-Jie, YAN Hong-Hao, KONG Ling-Jie. Effect of Ferrocene Precursor Mass on Gaseous Detonation Synthesisof Carbon Nanotubes[J]. Chinese Journal of High Pressure Physics, 2017, 31(4): 389-395. doi: 10.11858/gywlxb.2017.04.006

Citation:

YANG Rui, LI Xiao-Jie, YAN Hong-Hao, KONG Ling-Jie. Effect of Ferrocene Precursor Mass on Gaseous Detonation Synthesisof Carbon Nanotubes[J]. Chinese Journal of High Pressure Physics, 2017, 31(4): 389-395. doi: 10.11858/gywlxb.2017.04.006

Citation:

PDF( 3184 KB)

Effect of Ferrocene Precursor Mass on Gaseous Detonation Synthesisof Carbon Nanotubes

doi: 10.11858/gywlxb.2017.04.006

YANG Rui^1
,,
LI Xiao-Jie^{1, 2},
YAN Hong-Hao^{1,*
,
,},
KONG Ling-Jie¹

1.
Department of Engineering Mechanics, Dalian University of Technology, Dalian 116024, China
2.
State Key Laboratory of Structural Analysis for Industrial Equipment, Dalian University of Technology, Dalian 116024, China

Received Date: 05 Sep 2016
Rev Recd Date: 31 Oct 2016

Abstract

Abstract

In the present study we studied the influence of the mass of ferrocene precursors on the synthesis of carbon nanotubes with methane and oxygen as the explosive sources.The morphology and structure of the carbon nanotubes were characterized using X-ray diffraction, transmission electron microscopy and high resolution transmission electron microscopy technologies.The results indicate that when the ferrocene quantity is small only carbon coated iron nanoparticles exist in the products.With the increase of the ferrocene mass, carbon nanotubes are gradually produced with their diameters ranging from 10 to 50 nm, which are multi-walled carbon nanotubes.With the increase of the precursor mass, the degree of the graphitization of the carbon nanotubes is also increased but the structural defects are reduced.In addition, by the thermogravimetric analysis of the synthetic product, it can be concluded that the gaseous detonation synthesis of carbon nanotubes has a great ability of oxygen absorption, and the content of carbon nanotube in the sample is about 26%.
- carbon-encapsulated iron,
- carbon nanotubes,
- ferrocene,
- gaseous detonation method

FullText(HTML)

References(24)

References

[1]	IIJIMA S.Helical microtubules of graphitic carbon[J]. Nature, 1991, 354(6348):56-58. doi: 10.1038/354056a0
[2]	WALTERS D A, ERCSON L M, CASAVANT M J, et al.Elastic strain of freely suspended single-wall carbon nanotube ropes[J]. Appl Phys Lett, 1999, 74(25):3803-3805. doi: 10.1063/1.124185
[3]	AJAYAN P M, SCHADLER L S, GIANNARIS C, et al.Single-walled carbon nanotube-polymer composites:strength and weakness[J]. Adv Mater, 2000, 12(10):750-753. doi: 10.1002/(ISSN)1521-4095
[4]	DAI H J, HAFNER J H, RINZLER A G, et al.Nanotubes as nanoprobes in scanning probe microscopy[J]. Nature, 1996, 384(6605):147-150. doi: 10.1038/384147a0
[5]	EBBESEN T W, AJAYAN P M.Large-scale synthesis of carbon nanotubes[J]. Nature, 1992, 358(6383):220-222. doi: 10.1038/358220a0
[6]	IVANOV V, FONSECA A, NAGY J B.Catalytic production and purification of nanotubes having fullerene-scale diameters[J]. Carbon, 1995, 33(12):1727-1738. doi: 10.1016/0008-6223(95)00132-1
[7]	SEN R, GOVINDARAJ A, RAO C N R.Carbon nanotubes by the metallocene route[J]. Chem Phys Lett, 1997, 267(3):276-280. http://www.sciencedirect.com/science/article/pii/S0009261497000808
[8]	李莉香, 李峰, 英哲, 等.纳米碳管/聚合物功能复合材料[J].新型炭材料, 2003, 18(1):69-74. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=xxtcl200301013 LI L X, LI F, YING Z, et al.Carbon nanotube/polymer functional composite[J]. New Carbon Materials, 2003, 17(1):69-74. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=xxtcl200301013
[9]	戴贵平, 刘敏, 王茂章, 等.纳米碳管电化学储氢的研究进展[J].新型炭材料, 2002, 17(3):70-74. http://d.old.wanfangdata.com.cn/Periodical/xxtcl200203015 DAI G P, LIU M, WANG M Z, et al.Research on progress of electrochemical hydrogen storage in carbon nanotubes[J]. New Carbon Materials, 2002, 17(3):70-74. http://d.old.wanfangdata.com.cn/Periodical/xxtcl200203015
[10]	WANG S D, CHANG M H, DER L K M, et al.Synthesis of carbon nanotubes by arc discharge insodium chloride solution[J]. Carbon, 2005, 43(8):1778-1814. doi: 10.1016/j.carbon.2005.01.020
[11]	GUO T, NIKOLAEV P, THESS A, et al.Catalytic growth of single-walled manotubes by laser vaporization[J]. Chem Phys Lett, 1993, 243(1/2):49-54. http://www.sciencedirect.com/science/article/pii/000926149500825O
[12]	BHATIA R, PRASAD V.Synthesis of multiwall carbon nanotubes by chemical vapor deposition of ferrocene alone[J]. Solid State Commun, 2010, 150(7):311-315. doi: 10.1016-j.ssc.2009.11.023/
[13]	VANDER WAL R L, TIEICH T M, CURTIS V E.Diffusion flame synthesis of single-walled carbon nanotubes[J]. J Chem Phys, 2000, 323(3):217-223. http://www.sciencedirect.com/science/article/pii/S0009261400005224
[14]	刘远超, 孙保民, 丁兆勇, 等.V型热解火焰合成碳纳米管的催化剂选择与分析[J].工程热物理学报, 2009, 30(4):1506-1510. http://d.old.wanfangdata.com.cn/Periodical/gcrwlxb200904043 LIU Y C, SUN B M, DING Z Y, et al.Catalyst selection and analysis in Ⅴ-type pyrolysis flame synthesis carbon nanotubes[J]. Journal of Engineering Thermophysics, 2009, 30(4):1506-1510. http://d.old.wanfangdata.com.cn/Periodical/gcrwlxb200904043
[15]	潘春旭, YUAN L M, SAITO K.扩散火焰合成碳纳米管研究[J].新型炭材料, 2001, 16(3):24-27. http://d.old.wanfangdata.com.cn/Periodical/xxtcl200103005 PAN C X, YUAN L M, SAITO K.Study of nanotubes synthesis from diffusion flame[J]. New Carbon Materials, 2001, 16(3):24-27. http://d.old.wanfangdata.com.cn/Periodical/xxtcl200103005
[16]	WOO S K, HONG Y T, KWON O C.Flame synthesis of carbon nanotubes using a double-faced wall stagnation flow burner[J]. Carbon, 2009, 47(3):912-916. doi: 10.1016/j.carbon.2008.11.052
[17]	LUO N, LI X J, WANG X H, et al.Preparation and magnetic behavior of carbon-encapsulated iron nanoparticles by detonation method[J]. Compos Sci Technol, 2009, 69(15/16):2554-2558. http://www.sciencedirect.com/science/article/pii/S026635380900284X
[18]	李晓杰, 罗宁, 闫鸿浩, 等.爆轰法制备碳包覆铁镍合金纳米颗粒及其表征[J].稀有金属材料与工程, 2010, 39(Suppl 1):429-433. http://d.old.wanfangdata.com.cn/Periodical/xyjsclygc2010z1103 LI X J, LUO N, YAN H H, et al.Preparation of carbon-encapsulated ferronickel nanoparticles by detonation method and its characterization[J]. Rare Metal Materials and Engineering, 2010, 39(Suppl 1):429-433. http://d.old.wanfangdata.com.cn/Periodical/xyjsclygc2010z1103
[19]	罗宁, 李晓杰, 王小红, 等.碳包覆镍/钴纳米颗粒的爆轰合成法[J].爆炸与冲击, 2010, 30(4):390-394. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=bzycj201004009 LUO N, LI X J, WANG X H, et al.Detonation synthesis of carbon-encapsulated nickel/cobalt nanoparticles[J]. Explosion and Shock Waves, 2010, 30(4):390-394. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=bzycj201004009
[20]	罗宁, 李晓杰, 闫鸿浩, 等.爆轰合成碳包覆钴、镍磁性纳米颗粒的探索[J].高压物理学报, 2009, 23(6):415-420. doi: 10.3969/j.issn.1000-5773.2009.06.003 LUO N, LI X J, YAN H H, et al.Detonation synthesis of carbon encapsulated cobalt/nickel nanoparticles[J]. Chinese Journal of High Pressure Physics, 2009, 23(6):415-420. doi: 10.3969/j.issn.1000-5773.2009.06.003
[21]	李晓杰, 张晓军, 罗宁, 等.爆轰法合成碳包覆纳米铜颗粒[J].爆炸与冲击, 2012, 32(2):174-178. doi: 10.3969/j.issn.1001-1455.2012.02.010 LI X J, ZHANG X J, LUO N, et al.Synthesis of carbon-encapsulated copper nanoparticles by detonation method[J]. Explosion and Shock Waves, 2012, 32(2):174-178. doi: 10.3969/j.issn.1001-1455.2012.02.010
[22]	AJAYAN P M.Nanotubes from carbon[J]. Chem Rev, 1999, 99(7):1787-1799. doi: 10.1021/cr970102g
[23]	卢怡, 朱珍平, 刘振宇.催化剂对爆炸法合成碳纳米管的影响[J].新型炭材料, 2004, 19(1):1-6. http://d.old.wanfangdata.com.cn/Periodical/xxtcl200401001 LU Y, ZHU Z P, LIU Z Y.Effect of catalyst on the growth of carbon nanotubes using a detonation approach[J]. New Carbon Materials, 2004, 19(1):1-6. http://d.old.wanfangdata.com.cn/Periodical/xxtcl200401001
[24]	陈萍, 张鸿斌, 林国栋, 等.催化裂解CH₄或CO制碳纳米管结构性能的谱学表征[J].高等学校化学学报, 1998, 19(5):765-769. doi: 10.3321/j.issn:0251-0790.1998.05.013 CHEN P, ZHAN H B, LIN G D, et al.Studies on structure and property of carbon-nanotubes formed catalytically from decomposition of CH₄ or CO[J]. Chemical Journal of Chinese Universities, 1998, 19(5):765-769. doi: 10.3321/j.issn:0251-0790.1998.05.013

Relative Articles

Supplements(0)

Cited By

Proportional views

Proportional views

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Figures(5) / Tables(2)

Get Citation

PDF

XML

Article Metrics

Article views(6546) PDF downloads(223)

Effect of Ferrocene Precursor Mass on Gaseous Detonation Synthesisof Carbon Nanotubes

doi: 10.11858/gywlxb.2017.04.006

Abstract

References

Proportional views

Catalog

通讯作者: 陈斌, bchen63@163.com

Article Metrics

Proportional views

Related

Effect of Ferrocene Precursor Mass on Gaseous Detonation Synthesisof Carbon Nanotubes

doi: 10.11858/gywlxb.2017.04.006

Abstract

References

Proportional views

Catalog

通讯作者: 陈斌, bchen63@163.com

Article Metrics

Proportional views

Related

Export File

Citation

Format

Content