Volume 25 Issue 3
Oct 2013
Turn off MathJax
Article Contents
DU Yong-Hui, ZHANG Tie-Chen, ZHANG Wei-Sen. The Study on Black cBN Synthesis with Different Systems[J]. Chinese Journal of High Pressure Physics, 2011, 25(3): 242-246 . doi: 10.11858/gywlxb.2011.03.008
Citation: DU Yong-Hui, ZHANG Tie-Chen, ZHANG Wei-Sen. The Study on Black cBN Synthesis with Different Systems[J]. Chinese Journal of High Pressure Physics, 2011, 25(3): 242-246 . doi: 10.11858/gywlxb.2011.03.008

The Study on Black cBN Synthesis with Different Systems

doi: 10.11858/gywlxb.2011.03.008
More Information
  • Corresponding author: DU Yong-Hui
  • Received Date: 23 Feb 2010
  • Rev Recd Date: 27 Oct 2010
  • Publish Date: 15 Jun 2011
  • As well known, cubic boron nitride display more integrated morphology and larger crystal sizes with the color burn. In this paper, black cBN crystals were synthesized in the systems of Mg+hBN, LiH+hBN, Li3N+hBN+B and B+Li3N, respectively. Optical microscope (OM), X-ray diffraction and Raman spectroscopy were used to make a comparison with different black cBN crystals on the aspect of the synthetic condition, crystal morphology, grain size and residual stress. The results showed that the synthesized cBN with the different system exhibited obvious difference. In order to optimize the cBN synthesis, the appropriate system should be chosen according to diverse demands in practical applications.

     

  • loading
  • Sachdev H, Tang X, Haubner R, et al. Pathways to cBN from Melts at Atmospheric Pressure [J]. Refractory Metals Hard Materials, 1998, 16: 243-251.
    Taniguchi T, Yamaoka T. Spontaneous Nucleation of Cubic Boron Nitride Single Crystal by Temperature Gradiednt Method under High Pressure [J]. J Crys Growth, 2001, 222: 549-557.
    Lorenz H, Orgzall I. Influence of the Initial Crystallinity on the High Pressure-High Temperature Phase Transition in Boron Nitride [J]. Acta Mater, 2004, 52: 1909-1916.
    Solozhenko V L, Turkevich V Z, Novikov N V, et al. On the Cubic Crystallization in Fluid Systems [J]. Phys Chem Chem Phys, 2004, 6: 3900-3902.
    Yu M Y, Cui D L, Kai L, et al. Hydrothermal Synthesis of Cubic Boron Nitride Crystals [J]. Mater Sci Eng B, 2005, 121: 166-169.
    Singhala S K, Gonnab Vonder J, Noverb G, et al. Synthesis of Cubic Boron nitride at Reduced Pressures in the Presence of Co[(NH3)6]Cl3 and NH4F [J]. Diam Relat Mater, 2005, 14(8): 1389-1394.
    Endo T, Fukunaga O. Pressure-Temperature Region of Cubic BN in the System BN-Mg [J]. J Mater Sci, 1979, 14: 1375-1380.
    Wang X C, Jia X P, Zhang T C, et al. cBN Synthesis in the System of hBN-Mg and Bonded Water [J]. Diam Relat Mater, 2003, 12: 57-60.
    Gladkaya I S, Kremkova G N, Bendeliani N A. The Phase Transition of hBN-cBN in the B-N-H-O System [J]. Diam Relat Mater, 1996, 5: 1440-1443.
    Gameza L M, Shipilo V B, Savchuk V A. Investagation of Sulphur Additions on Kinetic Processes of Cubic Boron Nitride Crystallization in the Li-B-N-H System [J]. Diam Relat Mater, 1998, 7: 32-34.
    Solozhenko V L. Synchrotron Radiation Studies of the Kinetics of cBN Crystallization in the NH4F-BN System [J]. Phys Chem Chem Phys, 2002, 4: 1033-1035.
    Turkevich V, Taniguchi T, Andreev A, et al. Kinetics and Mechanism of Cubic Boron Nitride Formation in the AlN-BN System at 6 GPa [J]. Diam Relat Mater, 2004, 13: 64-68.
    Sanjurjo J A, Lopez-Cruz E. Dependence on Volume of the Phonon Frequencies and the Effective Charges of Several Ⅲ-Ⅴ Semiconductors [J]. Phys Rev B, 1983, 28: 4579-4582.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views(7737) PDF downloads(585) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return