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Chinese Journal of High Pressure Physics  > 2011  >  25(2): 104-110 .
LU Feng-Guo, QIU Li-Xia, DING Zhan-Hui, GUO Xing-Yuan, Lü Yang, ZHAO Xu-Dong, LIU Xiao-Yang. High-Pressure Synthesis and Properties Characterization of ZrN-ZrB2 Nanocomposites[J]. Chinese Journal of High Pressure Physics, 2011, 25(2): 104-110 . doi: 10.11858/gywlxb.2011.02.002
Citation: LU Feng-Guo, QIU Li-Xia, DING Zhan-Hui, GUO Xing-Yuan, Lü Yang, ZHAO Xu-Dong, LIU Xiao-Yang. High-Pressure Synthesis and Properties Characterization of ZrN-ZrB2 Nanocomposites[J]. Chinese Journal of High Pressure Physics, 2011, 25(2): 104-110 . doi: 10.11858/gywlxb.2011.02.002
shu

High-Pressure Synthesis and Properties Characterization of ZrN-ZrB2 Nanocomposites

doi: 10.11858/gywlxb.2011.02.002
  • 1.

    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China;

  • 2.

    College of Physics, Jilin University, Changchun 130023, China;

  • 3.

    State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, China

More Information
  • Corresponding author: DING Zhan-Hui
  • Received Date: 28 Jun 2010
  • Rev Recd Date: 28 Sep 2010
  • Publish Date: 15 Apr 2011
    Abstract
  • Combining high-energy ball milling and high-pressure high-temperature technique, high-dense ZrN-ZrB2 nanocomposites have been synthesized using Zr and h-BN powders as raw materials. The structures of product materials were studied through X-ray diffraction, high resolution transmission electron microscopy and Raman spectroscopy measurements. The result showed that only ZrNx can be synthesized during mechanical alloying process, which can be explained by the thermodynamics and kinetics of reaction of Zr atoms with N and B atoms. ZrN-ZrB2 nanocomposites synthesized at 5 GPa and 1 300 ℃ using 10 h ball-milled powder mixture show excellent mechanical and electrical properties. The microhardness, thermal expansion coefficient and thermal coefficient of resistivity of ZrN-ZrB2 composites are 17 GPa, 7.5710-6 ℃-1 and 8.84610-4 ℃-1, respectively.

     

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