Volume 23 Issue 5
Apr 2015
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Article Contents
SHEN Xi, SHEN Jun, YOU Shu-Jie, YANG Liu-Xiang, TANG Ling-Yun, LI Yan-Chun, LIU Jing, YANG Hua, ZHOU Wei-Ya, JIN Chang-Qing, et al.. Phase Transition of Zn2SnO4 Nanowires under High Pressure[J]. Chinese Journal of High Pressure Physics, 2009, 23(5): 327-331 . doi: 10.11858/gywlxb.2009.05.002
Citation: SHEN Xi, SHEN Jun, YOU Shu-Jie, YANG Liu-Xiang, TANG Ling-Yun, LI Yan-Chun, LIU Jing, YANG Hua, ZHOU Wei-Ya, JIN Chang-Qing, et al.. Phase Transition of Zn2SnO4 Nanowires under High Pressure[J]. Chinese Journal of High Pressure Physics, 2009, 23(5): 327-331 . doi: 10.11858/gywlxb.2009.05.002

Phase Transition of Zn2SnO4 Nanowires under High Pressure

doi: 10.11858/gywlxb.2009.05.002
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  • Corresponding author: SHEN Xi
  • Received Date: 25 Mar 2009
  • Rev Recd Date: 25 Mar 2009
  • Publish Date: 15 Oct 2009
  • In situ high-pressure angle dispersive X-ray diffraction (ADXRD) experiments on inverse spinel Zn2SnO4 (ZTO) nanowires were carried out in a diamond anvil cell (DAC) at room temperature. The crystal symmetry becomes lower at around 12.9 GPa and an intermediate phase occurs. At about 32.7 GPa, a phase transition happens and a high-pressure phase appears. After high pressure treatment, the nanowires are broken into nanorods. Through fitting the Birch-Murnaghan equation, we obtained the bulk modulus B0=(168.69.7) GPa for the inverse spinel ZTO nanowires, assuming its first order derivative B0=4 at ambient pressure.

     

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