Volume 22 Issue 1
Apr 2015
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LI Ming-Fa, FAN Duan, SUN Zhen-Ya, TIAN Xu, CHEN Li-Ying, YE Xian-Xian. The Microstructure and Thermal Performance of Phenolic Resin (PF)/Rectorite (REC) Nanocomposites Produced by High Pressure Method[J]. Chinese Journal of High Pressure Physics, 2008, 22(1): 57-61 . doi: 10.11858/gywlxb.2008.01.013
Citation: LI Ming-Fa, FAN Duan, SUN Zhen-Ya, TIAN Xu, CHEN Li-Ying, YE Xian-Xian. The Microstructure and Thermal Performance of Phenolic Resin (PF)/Rectorite (REC) Nanocomposites Produced by High Pressure Method[J]. Chinese Journal of High Pressure Physics, 2008, 22(1): 57-61 . doi: 10.11858/gywlxb.2008.01.013

The Microstructure and Thermal Performance of Phenolic Resin (PF)/Rectorite (REC) Nanocomposites Produced by High Pressure Method

doi: 10.11858/gywlxb.2008.01.013
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  • Corresponding author: LI Ming-Fa
  • Received Date: 19 Feb 2007
  • Rev Recd Date: 08 Jun 2007
  • Publish Date: 05 Mar 2008
  • High pressure method was used to produce phenolic resin (PF)/rectorite (REC) nanocomposites. The microstructure and thermal performance of the nanocomposites was studied by X-ray diffraction (XRD), transmission electron microscope (TEM), and thermal analysis. The experimental results show that exfoiated resin/clay nanocomposites can be formed under high pressure conditions by the intercalation of polymeric molecules without interlayer polymerization. Morphological studies using TEM and XRD indicated that the clay particles within the phenolic resin was exfoliated and dispersed homogenously in the phenolic resin, and the thermal performance of the nanocomposites changed obviously.

     

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  • Okada A, Kawasumi M, Kurauchi T, et al. Synthesis and Characterization of a Nylon6-Clay Hybrid [J]. Polym Prepr, 1987, 28: 447.
    Kojima Y, Usuki A, Kawasumi M, et al. Synthesis of Nylon 6-Clay Hybrid by Montmorillonite Intercalated with -Caprolactam [J]. Polymer Sci Part A: Polymer Chem, 1993, 31(4): 983-986.
    Neng Q Z, Chuan K Y, Kang D Y. The Polymer/Silicate Layered Nanocomposites Prepared by Intercalation [P]. China Patent, CN1187506A, 1998.
    Qiao F, Li Q, Qi Z N, et al. Synthesis and Characterization of Nylon 6/Clay Nanocomposites [J]. Chinese Polymer Bulletin, 1997, (03): 135-143. (in Chinese)
    乔放, 李强, 漆宗能, 等. 聚酰胺/粘土纳米复合材料的制备、结构表征及性能研究 [J]. 高分子通报, 1997, (03): 135-143.
    Zhang Z Y, Zhao N, Wei W, et al. Preparation and Characterization of MMT/PMMA and MMT/PBA/PMMA Nanon Hybrid Materials [J]. Fine Chem, 2005, (03): 171-173. (in Chinese)
    张志毅, 赵宁, 魏伟, 等. MMT/PMMA和MMT/PBA/PMMA纳米杂化材料的制备和表征 [J]. 精细化工, 2005, (03): 171-173.
    Nah C, Han S H, Lee J, et al. Preparation and Properties of Montmorillonite-Based Polyimide Nanocomposites [J]. Polymer Inter, 2004, 53: 891-897.
    Privalko V P, Ponomarenko S M. Structure and Thermoelastic Behavior of Synthetic Rubber/Organoclay Nanocomposites [J]. Macromole Chem Phys, 2003, 204: 1480-1485.
    Gonzalez I, Eguiazbal J I, Nazbal J. New Clay-Reinforced Nanocomposites Based on a Polycarbonate/Polycaprolactone Blend [J]. Polymer Eng Sci, 2006, 46: 864-873.
    Aranda P, Mosqueda Y, Ruiz-hitzky E, et al. Electrical Characterization of Poly(Ethylene Oxide)-Clay Nanocomposites Prepared by Microwave Irradiation [J]. J Polymer Sci Part B: Polymer Physics, 2003, 41: 3249-3263.
    Chen K H, Yang S M. Synthesis of Epoxy-Montmorillonite Nanocomposite [J]. J Appl Polymer Sci, 2002, 86: 414-421.
    Chen G M, Li Q, Qi Z N, et al. Advance in Polymer Layered Silicate Nanocomposites [J]. 1999, (04): 1-10. (in Chinese)
    陈光明, 李强, 漆宗能, 等. 聚合物/层状硅酸盐纳米复合材料研究进展 [J]. 高分子通报, 1999, (04): 1-10.
    Santiago F, Mucientes A E, Osorio M, et al. Preparation of Composites and Nanocomposites Based on Bentonite and Poly(Sodium Acrylate). Effect of Amount of Bentonite on the Swelling Behaviour [J]. Euro Polymer J, 2007, 43(1): 1-9.
    Xiong J, Zheng Z, Jiang H, et al. Reinforcement of Polyurethane Composites with an Organically Modified Montmorillonite [J]. Composites Part A: Applied Science and Manufacturing, 2007, 38(1): 132-137.
    Wang S J, Liu L M, Fang P F, et al. Microstructure of Polymer-Clay Nanocomposites Studied by Positrons [J]. Radiation Physics and Chemistry, 2007, 76(2): 106-111.
    Kokabi M, Sirousazar M, Hassan Z M. Pva-Clay Nanocomposite Hydrogels for Wound Dressing [J]. Euro Polymer J, 2007, 43(3): 773-781.
    Si M, Zaitsev V, Goldman M, et al. Self-Extinguishing Polymer/Organoclay Nanocomposites [J]. Polymer Degradation and Stability, 2007, 92(1): 86-93.
    Barbosa R, Araujo E M, Melo T J, et al. Comparison of Flammability Behavior of Polyethylene/Brazilian Clay Nanocomposites and Polyethylene/Flame Retardants [J]. Materials Letters, 2007, 61(11-12): 2575-2578.
    Sun Z Y, Hu C, Li M F, et al. Study on Exfoliation of Rectorite Nanocrystal Layers by High Pressure Method [J]. Polymer Materials Science Engineering, 2006, (02): 213-219. (in Chinese)
    孙振亚, 胡纯, 黎明发, 等. 累托石纳米晶层的高压剥离研究 [J]. 高分子材料科学与工程, 2006, (2): 213-219.
    Sun Z Y, Hu C, Li M F, et al. Preparation of Intercalated Clay/Phenolic Resin Nanocomposites under High Pressure [J]. Journal of Wuhan University of Technology-Materials Science, 2006, 21(4): 83-86.
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