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Chinese Journal of High Pressure Physics  > 2007  >  21(3): 305-310 .
SONG Gong-Bao, WANG Mei-Li, MIAO Lan-Dong, LI Jian, ZHANG Bao-Shu. Direct Hydrothermal Synthesis and Luminescence Property of Titanate Nanotubes Doped with Eu3+ Ions[J]. Chinese Journal of High Pressure Physics, 2007, 21(3): 305-310 . doi: 10.11858/gywlxb.2007.03.015
Citation: SONG Gong-Bao, WANG Mei-Li, MIAO Lan-Dong, LI Jian, ZHANG Bao-Shu. Direct Hydrothermal Synthesis and Luminescence Property of Titanate Nanotubes Doped with Eu3+ Ions[J]. Chinese Journal of High Pressure Physics, 2007, 21(3): 305-310 . doi: 10.11858/gywlxb.2007.03.015
shu

Direct Hydrothermal Synthesis and Luminescence Property of Titanate Nanotubes Doped with Eu3+ Ions

doi: 10.11858/gywlxb.2007.03.015

  • Key Laboratory of Building Materials of Sichuan Province, Southwest University of Science and Technology, Mianyang 621010, China

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  • Corresponding author: SONG Gong-Bao
  • Received Date: 30 Apr 2006
  • Rev Recd Date: 08 Oct 2006
  • Publish Date: 05 Sep 2007
    Abstract
  • Pure titanate nanotubes and titanate nanotubes doped with Eu3+ ions were synthesized by hydrothermal method. In this process, the preparation of nanotubes is synchronously finished by doping with Eu3+ ions. The morphology, structure, thermal stability and luminescence property of titanate nanotubes were characterized by transmission electron microscope (TEM), X-ray diffraction (XRD), and photoluminescence instrument. The results show that the method is simple, stable and high-yield. The structure of the nanotube could be approximately indexed by (H,Na)2Ti3O7 or (H,Na)2(Ti,Eu)3O7. Treatment of high temperature will bring into big changes to structures of titanate nanotubes. When the calcine temperature is higher than 450 ℃, tubulous structure of titanate nanotube was destroyed and transformed into structure of anatase phase. Sample of TNT-Eu shows strong luminescence property. There exist three peaks (393.5 nm, 593 nm, 614 nm) in its luminescence spectrum which are associated to 5D0-7F1 and 5D0-7F2 Eu3+ electronic transition respectively.

     

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    • References(27)
  • Dagan G, Tomkiewicz M. Titanium Dioxide Aerogels for Photocatalytic Decontamination of Aquatic Environments [J]. J Phys Chem 1993, 97: 12651-12655.
    Regan B O, Graetzel M. A Low-Cost, High-Efficiency Solar Cell Based on Dye-Sensitized Colloidal TiO2 Films [J]. Nature, 1991, 353: 737-740.
    Hoyer P. Formation of a Titanium Dioxide Nanotube Array [J]. Langmuir, 1996, 12: 1411-1413.
    Jung J H, Kobayashi H, van Bommel K J C, et al. Creation of Novel Helical Ribbon and Double-Layered Nanotube TiO2 Structures Using an Organogel Template [J]. Chem Mater, 2002, 14: 1445-1447.
    Narayanasamy A, Maroni V A, Siegel R W. Raman-Spectroscopy of Nanophase TiO2 [J]. J Mater Res, 1989, 4: 1246-1250.
    Hoyer P. Semiconductor Nanotube Formation by a Two-Step Template Process [J]. Adv Mater, 1996, 8: 857-859.
    Lakshmi B B, Patrissi C J, Martin C R. Sol-Gel Template Synthesis of Semiconductor Oxide Micro- and Nanostructures [J]. Chem Mater, 1997, 9: 2544-2550.
    Michailowski A, AlMawlawi D, Cheng G S, et al. Highly Regular Anatase Nanotubule Arrays Fabricated in Porous Anodic Templates [J]. Chem Phys Lett, 2001, 349: 1-5.
    Kobayashi S, Hanabusa K, Hamasaki N, et al. Preparation of TiO2 Hollow-Fibers Using Supramolecular Assemblies [J]. Chem Mater, 2000, 12: 1523-1525.
    Hong J, Sun J Zh, Cao J, et al. Control of Microscopic Morphology and Structure of One Dimensional Titanium Dioxide Nanomaterials [J]. Chinese Journal of Materials Research, 2004, 18: 6-10. (in Chinese)
    洪剑, 孙景志, 曹健, 等. 一维TiO2纳米材料的微观形态与结构的控制 [J]. 材料研究学报, 2004, 18: 6-10.
    Imai H, Takei Y, Shimizu K, et al. Direct Preparation of Anatase TiO2 Nanotubes in Porous Alumina [J]. J Mater Chem, 1999, 9: 2971-2972.
    Kasuga T, Hiramatsu M, Hoson A. Formation of Titanium Oxide Nanotube [J]. Langmuir, 1998, 14: 3160-3163.
    Du G H, Chen Q, Che R C, et al. Preparation and Structure Analysis of Titanium Oxide Nanotubes [J]. Appl Phys Lett, 2001, 79: 3702-3704.
    Kasuga T, Hiramatsu M, Hoson A, et al. Titania Nanotubes Prepared by Chemical Processing [J]. Adv Mater, 1999, 11: 1307-1311.
    Yao B D, Chan Y F, Zhang X Y, et al. Formation Mechanism of TiO2 Nanotubes [J]. Appl Phys Lett, 2003, 82(2): 281-283.
    Yuan Z Y, Su B L. Titanium Oxide Nanotubes, Nanofibers and Nanowires [J]. Colloids and Surfaces A: Physicochem Eng Aspects, 2004, 241: 173-183.
    Yoshida R, Suzuki Y, Yoshikawa S. Effects of Synthetic Conditions and Heat-Treatment on the Structure of Partially Ion-Exchanged Titanate Nanotubes [J]. Mater Chem Phys, 2005, 91: 409-416.
    Suzuki Y, Pavasupree S, Yoshikawa S, et al. Natural Rutile-Derived Titanate Nanofibers Prepared by Direct Hydrothermal Processing [J]. J Mater Res, 2005, 20(4): 1063-1070.
    Bavykin D V, Parmon V N, Lapkina A A, et al. The Effect of Hydrothermal Conditions on the Mesoporous Structure of TiO2 Nanotubes [J]. J Mater Chem, 2004, 14: 3370-3377.
    Zhu Y C, Li H L, Koltypin Y, et al. Sonochemical Synthesis of Titania Whiskers and Nanotubes [J]. Chem Commun, 2001, 24: 2616-2617.
    Zhang S, Peng L M, Chen Q, et al. Formation Mechanism of H2Ti3O7 Nanotubes [J]. Phys Rev Lett, 2003, 91(25): 256103.
    Chen S Y, Ting C C, Hsieh W F. Comparison of Visible Fluorescence Properties between Sol-Gel Derived Er3+-Yb3+ and Er3+-Y3+ Co-Doped TiO2 Films [J]. Thin Solid Films, 2003, 434(1-2): 171-177.
    Frindell K L, Bartl M H, Robinson M R, et al. Visible and Near-IR Luminescence via Energy Transfer in Rare Earth Doped Mesoporous Titania Thin Films with Nanocrystalline Walls [J]. J Solid State Chem, 2003, 172(1): 81-88.
    Iakovlev S, Solterbeck C H, Es-Souni M, et al. Rare-Earth Ions Doping Effects on the Optical Properties of Sol-Gel Fabricated PbTiO3 Thin Films [J]. Thin Solid Films, 2004, 446(1): 50-53.
    Sun X M, Li Y D. Synthesis and Characterization of Ion-Exchangeable Titanate Nanotubes [J]. Chemistry-A European Journal, 2003, 9(10): 2229-2238.
    Conde-Gallardo A, Garca-Rocha M, Palomino-Merino R, et al. Photoluminescence Properties of Tb3+ and Eu3+ Ions Hosted in TiO2 Matrix [J]. Appl Surf Sci, 2003, 212-213: 583-588.
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