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WANG Jin-Bin, YANG Guo-Wei. Model of Structural Transformation in Synthesizing Nano-Crystalline Diamond with Pulsed-Laser Induced Liquid-Solid Interface Reaction[J]. Chinese Journal of High Pressure Physics, 1999, 13(2): 147-151 . doi: 10.11858/gywlxb.1999.02.012
Citation: WANG Jin-Bin, YANG Guo-Wei. Model of Structural Transformation in Synthesizing Nano-Crystalline Diamond with Pulsed-Laser Induced Liquid-Solid Interface Reaction[J]. Chinese Journal of High Pressure Physics, 1999, 13(2): 147-151 . doi: 10.11858/gywlxb.1999.02.012

Model of Structural Transformation in Synthesizing Nano-Crystalline Diamond with Pulsed-Laser Induced Liquid-Solid Interface Reaction

doi: 10.11858/gywlxb.1999.02.012
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  • Corresponding author: WANG Jin-Bin
  • Received Date: 20 Aug 1998
  • Rev Recd Date: 02 Nov 1998
  • Publish Date: 05 Jun 1999
  • The physical and chemical mechanisms of synthesizing diamond nanocrystallites with pulsed-laser induced liquid-solid interface reaction (PLIR) have been analyzed in this paper. At the initial stage of nano-crystalline diamond growth, the models of structural transformation from hexagonal to rhombohedral graphite at first and then to cubic diamond crystal nuclear, or from hexagonal graphite direct to cubic diamond have been developed. These models reasonably explain the physical and chemical mechanisms of synthesizing diamond nanocrystallites with pulsed-laser induced liquid-solid interface reaction from a kinetic view.

     

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