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LIU Fu-Sheng, CHEN Xian-Meng, CHEN Pan-Sen, SUN Yue, JING Fu-Qian. Equation of State of Liquid CO2 at High Temperature and High Densities[J]. Chinese Journal of High Pressure Physics, 1998, 12(1): 28-33 . doi: 10.11858/gywlxb.1998.01.005
Citation: LIU Fu-Sheng, CHEN Xian-Meng, CHEN Pan-Sen, SUN Yue, JING Fu-Qian. Equation of State of Liquid CO2 at High Temperature and High Densities[J]. Chinese Journal of High Pressure Physics, 1998, 12(1): 28-33 . doi: 10.11858/gywlxb.1998.01.005

Equation of State of Liquid CO2 at High Temperature and High Densities

doi: 10.11858/gywlxb.1998.01.005
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  • Corresponding author: LIU Fu-Sheng
  • Received Date: 28 Mar 1997
  • Rev Recd Date: 06 Nov 1997
  • Publish Date: 05 Mar 1998
  • In this work the shock compression behavior of liquid CO2 is investigated using the two-stage light-gas gun and the cryogenic target established by ourselves. Six new Hugoniot data ranging from 20~60 GPa are obtained. On the basis of these data points, the parameters in the effective potentials of CO2-CO2 and CO2-O are re-determined according to a statistical mechanics theory including chemical equilibrium. The significant mechanism which causes the p-V softening phenomena above 25 GPa is theoretically confirmed to be CO2CO+O.

     

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