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LIN Xiao-Min, YAO Bin, SU Wen-Hui. A Thermodynamic Study on the Crystallization Processes of Amorphous (Fe0.99,Mo0.01)78Si9B13 Alloy under High Pressrue[J]. Chinese Journal of High Pressure Physics, 1997, 11(4): 260-265 . doi: 10.11858/gywlxb.1997.04.005
Citation: LIN Xiao-Min, YAO Bin, SU Wen-Hui. A Thermodynamic Study on the Crystallization Processes of Amorphous (Fe0.99,Mo0.01)78Si9B13 Alloy under High Pressrue[J]. Chinese Journal of High Pressure Physics, 1997, 11(4): 260-265 . doi: 10.11858/gywlxb.1997.04.005

A Thermodynamic Study on the Crystallization Processes of Amorphous (Fe0.99,Mo0.01)78Si9B13 Alloy under High Pressrue

doi: 10.11858/gywlxb.1997.04.005
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  • Corresponding author: LIN Xiao-Min
  • Received Date: 14 Feb 1997
  • Rev Recd Date: 21 Jul 1997
  • Publish Date: 05 Dec 1997
  • Amorphous (Fe0.99,Mo0.01)78Si9B13 alloys were annealed for 30 min at a temperature between 600 K and 930 K under pressures of normal pressure to 7 GPa. It was found that precipitation temperature of their crystallization products of -Fe(Mo,Si), Fe3B and Fe2B alloys are related closely to the pressure used. Crystallization temperature of amorphous alloy and precipitation temperature of the metastable phase Fe3B decrease with increasing pressure at the present pressure condition. At certain temperature and pressure, the Fe3B alloy will transform into a stable phase Fe2B and its transition temperature changes with pressure. A thermodynamic mechanism on the crystallization of the amorphous (Fe0.99,Mo0.01)78Si9B13 alloy and the phase transition of the Fe3B to the Fe2B was discussed, and an equation of the phase transition from the Fe3B to the Fe2B was given.

     

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