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WU Rui-Qi, WANG Hui, YANG Guang-Qun, HUANG Rui. Studies of Crystallization of High Density Polyethylene under High Hydrostatic Pressure[J]. Chinese Journal of High Pressure Physics, 1989, 3(2): 165-171 . doi: 10.11858/gywlxb.1989.02.011
Citation: WU Rui-Qi, WANG Hui, YANG Guang-Qun, HUANG Rui. Studies of Crystallization of High Density Polyethylene under High Hydrostatic Pressure[J]. Chinese Journal of High Pressure Physics, 1989, 3(2): 165-171 . doi: 10.11858/gywlxb.1989.02.011

Studies of Crystallization of High Density Polyethylene under High Hydrostatic Pressure

doi: 10.11858/gywlxb.1989.02.011
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  • Corresponding author: WU Rui-Qi
  • Received Date: 08 Dec 1988
  • Rev Recd Date: 08 Dec 1988
  • Publish Date: 05 Jun 1989
  • High density polyethylene has been crystallized under a pressure 1 GPa to 2 GPa and cooled at 5 ℃ per minute from the melting point. The solids were analyzed at atmosphere pressure by DSC, SEM and WAXD. The data show that the crystalline content of the samples by WAXD increases to 89.9% from 68.2% of the original material. Extended chain lamellae have thickened from 14 nm to 25 nm. DSC and SEM observations show the existence of the extended chain lamellae. Controlling of high pressure and temperature is the key of the formation of extended-chain crystals.

     

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