ZrN-ZrB2纳米复合材料的高压制备及性能表征

陆凤国; 邱利霞; 丁战辉; 郭星原; 吕洋; 赵旭东; 刘晓旸

doi:10.11858/gywlxb.2011.02.002

ZrN-ZrB2纳米复合材料的高压制备及性能表征

doi: 10.11858/gywlxb.2011.02.002

1.
吉林大学无机合成与制备化学国家重点实验室，吉林长春 130012；
2.
吉林大学物理学院，吉林长春 130023；
3.
吉林大学超硬材料国家重点实验室，吉林长春 130012

详细信息

通讯作者:
丁战辉

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出版历程
- 收稿日期: 2010-06-28
- 修回日期: 2010-09-28
- 刊出日期: 2011-04-15

High-Pressure Synthesis and Properties Characterization of ZrN-ZrB2 Nanocomposites

1.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China;
2.
College of Physics, Jilin University, Changchun 130023, China;
3.
State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, China

More Information

Corresponding author: DING Zhan-Hui

摘要

摘要: 以金属锆粉（Zr）和六方氮化硼粉（h-BN）为原料，结合高能球磨和高温高压合成技术，制备出了ZrN-ZrB2纳米复合材料。利用X射线衍射、透射电镜和拉曼光谱等测试手段，对材料的结构和合成规律进行了研究。结果表明，高能球磨过程中只合成出了ZrNx，没有出现ZrB2，从N、B原子与Zr进行固态反应的热力学和动力学方面分析了原因。利用Zr与BN粉球磨10 h后的混料，在压力为5 GPa、温度为1 300 ℃的条件下，制备出了具有高致密度的ZrN-ZrB2纳米复合材料。其维氏显微硬度（17 GPa）、热膨胀系数（7.5710-6 ℃-1）和电阻率-温度系数（8.84610-4 ℃-1）等材料参数的测量结果表明，ZrN-ZrB2复合材料是一种集优良的力学、热学和电学性能于一体的纳米复合材料。
- 氮化锆 /
- 硼化锆 /
- 高温高压 /
- 纳米复合材料
Abstract: Combining high-energy ball milling and high-pressure high-temperature technique, high-dense ZrN-ZrB2 nanocomposites have been synthesized using Zr and h-BN powders as raw materials. The structures of product materials were studied through X-ray diffraction, high resolution transmission electron microscopy and Raman spectroscopy measurements. The result showed that only ZrNx can be synthesized during mechanical alloying process, which can be explained by the thermodynamics and kinetics of reaction of Zr atoms with N and B atoms. ZrN-ZrB2 nanocomposites synthesized at 5 GPa and 1 300 ℃ using 10 h ball-milled powder mixture show excellent mechanical and electrical properties. The microhardness, thermal expansion coefficient and thermal coefficient of resistivity of ZrN-ZrB2 composites are 17 GPa, 7.5710-6 ℃-1 and 8.84610-4 ℃-1, respectively.
- ZrN /
- ZrB2 /
- high-pressure and high temperature /
- nanocomposites

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参考文献(27)

Pierson H O. Handbook of Refractory Carbides and Nitrides: Properties, Characteristics, Processing and Applications [M]. New Jersey: Noyes Publications, 1996: 511-538.

Wu D, Zhang Z, Fu D, et al. Structure, Electrical and Chemical Properties of Zirconium Nitride Films Deposited by DC Reactive Magnetron Sputtering [J]. Appl Phys A, 1997, 64(6): 593-595.

Kelesoglu E, Mitterer C, Kazmanli M K, et al. Microstructure and Properties of Nitride and Diboride Hard Coatings Deposited under Intense Mild-Energy Ion Bombardment [J]. Surf Coat Technol, 1999, 116-119: 133-140.

Sue J A, Chang T P. Friction and Wear Behavior of Titanium Nitride, Zirconium Nitride and Chromium Nitride Coatings at Elevated Temperatures [J]. Surf Coat Technol, 1995, 76-77: 61-69.

Sakamoto I, Maruno S, Jin P. Preparation and Microstructure of Reactively Sputtered Ti1-xZrxN Films [J]. Thin Solid Films, 1993, 228(1-2): 169-172.

Wang C C, Akbar S A, Chen W, et al. Electrical Properties of High-Temperature Oxides, Borides, Carbides, and Nitrides [J]. J Mater Sci, 1995, 30(7): 1627-1641.

Constantin R, Miremad B. Performance of Hard Coatings, Made by Balanced and Unbalanced Magnetron Sputtering, for Decorative Applications [J]. Surf Coat Technol, 1999, 120-121: 728-733.

Benia H M, Guemmaz M, Schmerber G, et al. Investigations on Non-Stoichiometric Zirconium Nitrides [J]. Appl Surf Sci, 2002, 200(1-4): 231-238.

Gotoh Y, Shiigi T, Nagao M, et al. Influence of Ambient Nitrogen Pressure on the Property of Zirconium Nitride Thin Films in Ion Beam Assisted Deposition [A]//International Conference on Ion Implantation Technology Proceedings [C]. Kyoto, Japan, 1998, 2: 1125-1128.

Chou W J, Yu G P, Huang J H. Bias Effect of Ion-Plated Zirconium Nitride Film on Si (100) [J]. Thin Solid Films, 2002, 405(1-2): 162-169.

Kosolapova T Y. Handbook of High Temperature Compounds: Properties, Production, Applications [M]. New York: Hemisphere Publishing Corporation, 1990.

Monteverde F, Guicciardi S, Bellosi A. Advances in Microstructure and Mechanical Properties of Zirconium Diboride Based Ceramics [J]. Mater Sci Eng A, 2003, 15(1-2): 310-319.

Monteverde F, Bellosi A, Scatteia L. Processing and Properties of Ultra-High Temperature Ceramics for Space Applications [J]. Mater Sci Eng A, 2008, 485(1-2): 415-421.

Yang B, Lu F G, Zhao X D, et al. Introduction and Pressure Calibration of 1000 Tons Walker Module High Pressure and High Temperature Apparatus [J]. Chinese Journal of High Pressure Physics. (in Chinese, to be published)

杨斌, 陆凤国, 赵旭东, 等. 1000吨Walker型高温高压装置的使用与压力标定 [J]. 高压物理学报. (待发表)

Dai Y N. Binary Alloy Phase Diagrams [M]. Beijing: Science Press, 2009: 162-820. (in Chinese)

戴永年. 二元合金相图 [M]. 北京: 科学出版社, 2009: 162-820.

Constable C P, Yarwood J, Mnz W D. Raman Microscopic Studies of PVD Hard Coatings [J]. Surf Coat Technol, 1999, 116-119: 155-159.

Spengler W, Kaiser R. First and Second Order Raman Scattering in Transition Metal Compounds [J]. Solid State Commun, 1976, 18(7): 881-884.

Kourouklis G A, Liarokapis E. Pressure and Temperature Dependence of the Raman Spectra of Zirconia and Hafnia [J]. J Am Ceram Soc, 1991, 74(3): 520-523.

Quintard P E, Barberis P, Mirgorodsky A P, et al. Comparative Lattice-Dynamical Study of the Raman Spectra of Monoclinic and Tetragonal Phases of Zirconia and Hafnia [J]. J Am Ceram Soc, 2002, 85(7): 1745-1749.

Xu R R, Pang W Q, Huo Q S. Inorganic Synthesis and Preparative Chemistry [M]. 2nd ed. Beijing: High Education Press, 2009: 221-228. (in Chinese)

徐如人, 庞文琴, 霍启升. 无机合成与制备化学 [M]. 第二版. 北京: 高等教育出版社, 2009: 221-228.

Monteverde F, Bellosi A, Guicciardi S. Processing and Properties of Zirconium Diboride-Based Composites [J]. J Eur Ceram Soc, 2002, 22(3): 279-288.

Samsonov G V, Grebenkina V G. Temperature Coefficient of Electroresistance of Some High-Melting Compounds [J]. Powder Metall Met Ceram, 1968, 7(2): 107-111.

Zimmermann J W, Hilmas G E, Fahrenholtz W G, et al. Thermophysical Properties of ZrB2 and ZrB2-SiC Ceramics [J]. J Am Ceram Soc, 2008, 91(5): 1405-1411.

Rahman M, Wang C C, Chen W, et al. Electrical Resistivity of Titanium Diboride and Zirconium Diboride [J]. J Am Ceram Soc, 1995, 78(5): 1380-1382.

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