High Pressure Investigation on the Alkaline-Earth Metal Hydride

WU Gang; HUANG Xiao-Li; LI Xin; HUANG Yan-Ping; LIU Ming-Kun; CUI Tian

doi:10.11858/gywlxb.2017.06.002

Volume 31 Issue 6

Nov 2017

Turn off MathJax

Article Contents

Chinese Journal of High Pressure Physics > 2017 > 31(6): 682-691.

WU Gang, HUANG Xiao-Li, LI Xin, HUANG Yan-Ping, LIU Ming-Kun, CUI Tian. High Pressure Investigation on the Alkaline-Earth Metal Hydride[J]. Chinese Journal of High Pressure Physics, 2017, 31(6): 682-691. doi: 10.11858/gywlxb.2017.06.002

Citation:

WU Gang, HUANG Xiao-Li, LI Xin, HUANG Yan-Ping, LIU Ming-Kun, CUI Tian. High Pressure Investigation on the Alkaline-Earth Metal Hydride[J]. Chinese Journal of High Pressure Physics, 2017, 31(6): 682-691. doi: 10.11858/gywlxb.2017.06.002

Citation:

PDF( 2815 KB)

High Pressure Investigation on the Alkaline-Earth Metal Hydride

doi: 10.11858/gywlxb.2017.06.002

State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012, China

Received Date: 13 Jul 2017
Rev Recd Date: 25 Jul 2017

Abstract

Abstract

As an effective way to realize metal hydrogen and high-temperature superconductors, the metalization and superconductivity of hydrogen-rich compounds have become one of the hot spots of physics and materials science.In practical application, hydrogen-rich compounds are also potential hydrogen storage materials.The study of the structure and properties of hydrogen-rich compounds under high pressure is considered to be an effective means to enhance their hydrogen storage performance.In this paper, high pressure experimental and theoretical researches on the second main group hydrides, a typical kind of rich hydrogen compounds, were briefly introduced, including high pressure structural phase transition, the stability of the new structure, the mechanism of metalization.The effects of different hydrogen motifs on superconductivity were also discussed.
- metal hydride,
- structural phase transition,
- metallization,
- high temperature superconductivity

FullText(HTML)

References(52)

References

[1]	SCHLAPBACH L, ZÜTTEL A.Hydrogen-storage materials for mobile applications[J]. Nature, 2001, 414(6861):353-358. doi: 10.1038/35104634
[2]	SONG Y.New perspectives on potential hydrogen storage materials using high pressure[J]. Phys Chem Chem Phys, 2013, 15(35):14524-14547. doi: 10.1039/c3cp52154k
[3]	HUOT J, LIANG G, BOILY S, et al.Structural study and hydrogen sorption kinetics of ball-milled magnesium hydride[J]. J Alloy Compd, 1999, 293:495-500. http://www.sciencedirect.com/science/article/pii/S0925838899004740
[4]	LIANG G, HUOT J, BOILY S, et al.Catalytic effect of transition metals on hydrogen sorption in nanocrystalline ball milled MgH₂-Tm (Tm=Ti, V, Mn, Fe and Ni) systems[J]. J Alloy Compd, 1999, 292(1):247-252. https://www.sciencedirect.com/science/article/abs/pii/S0925838899004429
[5]	VAJEESTON P, RAVINDRAN P, KJEKSHUS A, et al.Pressure-induced structural transitions in MgH₂[J]. Phys Rev Lett, 2002, 89(17):175506. doi: 10.1103/PhysRevLett.89.175506
[6]	RAFIEE M A.A theoretical study of MgH₂ ambient and high-pressure phases using NQCC parameters[J]. Russ J Phys Chem A, 2014, 88(13):2359-2362. doi: 10.1134/S0036024414130172
[7]	WIGNER E, HUNTINGTON H B.On the possibility of a metallic modification of hydrogen[J]. J Chem Phys, 1935, 3(12):764-770. doi: 10.1063/1.1749590
[8]	ASHCROFT N W.Metallic hydrogen:a high-temperature superconductor?[J]. Phys Rev Lett, 1968, 21(26):1748. doi: 10.1103/PhysRevLett.21.1748
[9]	NARAYANA C, LUO H, ORLOFF J, et al.Solid hydrogen at 342 GPa:no evidence for an alkali metal[J]. Nature, 1998, 393(6680):46-49. doi: 10.1038/29949
[10]	LOUBEYRE P, OCCELLI F, LETOULLEC R.Optical studies of solid hydrogen to 320 GPa and evidence for black hydrogen[J]. Nature, 2002, 416(6881):613-617. doi: 10.1038/416613a
[11]	EREMETS M I, TROYAN I A.Conductive dense hydrogen[J]. Nat Mater, 2011, 10(12):927-931. doi: 10.1038/nmat3175
[12]	KLUG D D, YAO Y.Metallization of solid hydrogen:the challenge and possible solutions[J]. Phys Chem Chem Phys, 2011, 13(38):16999-17006. doi: 10.1039/c1cp21791g
[13]	MCMAHON J M, CEPERLEY D M.Ground-state structures of atomic metallic hydrogen[J]. Phys Rev Lett, 2011, 106(16):165302. doi: 10.1103/PhysRevLett.106.165302
[14]	ZHA C S, LIU Z, HEMLEY R J.Synchrotron infrared measurements of dense hydrogen to 360 GPa[J]. Phys Rev Lett, 2012, 108(14):146402. doi: 10.1103/PhysRevLett.108.146402
[15]	EREMETS M I, TROYAN I A, LERCH P, et al.Infrared study of hydrogen up to 310 GPa at room temperature[J]. High Pressure Res, 2013, 33(2):377-380. doi: 10.1080/08957959.2013.794229
[16]	DIAS R P, SILVERA I F.Observation of the Wigner-Huntington transition to metallic hydrogen[J]. Science, 2017, 355(6326):715-718. doi: 10.1126/science.aal1579
[17]	ASHCROFT N W.Hydrogen dominant metallic alloys:high temperature superconductors?[J]. Phys Rev Lett, 2004, 92(18):187002. doi: 10.1103/PhysRevLett.92.187002
[18]	DROZDOV A P, EREMETS M I, TROYAN I A, et al.Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system[J]. Nature, 2015, 525(7567):73-76. doi: 10.1038/nature14964
[19]	DUAN D F, LIU Y X, TIAN F B, et al.Pressure-induced metallization of dense (H₂S)₂H₂ with high-T_c superconductivity[J]. Sci Rep, 2014, 4:6968. doi: 10.1038/srep06968
[20]	DUAN D F, HUANG X L, TIAN F B, et al.Pressure-induced decomposition of solid hydrogen sulfide[J]. Phys Rev B, 2015, 91(18):180502. doi: 10.1103/PhysRevB.91.180502
[21]	WANG H, JOHN S T, TANAKA K, et al.Superconductive sodalite-like clathrate calcium hydride at high pressures[J]. Proc Natl Acad Sci, 2012, 109(17):6463-6466. doi: 10.1073/pnas.1118168109
[22]	ARMSTRONG D R, JAMIESON J, PERKINS P G.The electronic structures of polymeric beryllium hydride and polymeric boron hydride[J]. Theoretica Chimica Acta, 1979, 51(2):163-172. doi: 10.1007/BF00554099
[23]	SMITH G S, JOHNSON Q C, SMITH D K, et al.The crystal and molecular structure of beryllium hydride[J]. Solid State Commun, 1988, 67(5):491-494. doi: 10.1016/0038-1098(84)90168-6
[24]	VAJEESTON P, RAVINDRAN P, KJEKSHUS A, et al.Structural stability of BeH₂ at high pressures[J]. Appl Physics Lett, 2004, 84(1):34-36. doi: 10.1063/1.1637967
[25]	AHART M, YARGER J L, LANTZKY K M, et al.High-pressure Brillouin scattering of amorphous BeH₂[J]. J Chem Phys, 2006, 124(1):014502. doi: 10.1063/1.2138692
[26]	BORTZ M, BERTHEVILLE B, BÖTTGER G, et al.Structure of the high pressure phase γ-MgH₂ by neutron powder diffraction[J]. J Alloy Compd, 1999, 287(1/2):L4-L6. http://www.sciencedirect.com/science/article/pii/S0925838899000286
[27]	VAJEESTON P, RAVINDRAN P, HAUBACK B C, et al.Structural stability and pressure-induced phase transitions in MgH₂[J]. Phys Rev B, 2006, 73(22):224102. doi: 10.1103/PhysRevB.73.224102
[28]	MORIWAKI T, AKAHAMA Y, KAWAMURA H, et al.Structural phase transition of rutile-type MgH₂ at high pressures[J]. J Phy Soc Jpn, 2006, 75(7):074603. doi: 10.1143/JPSJ.75.074603
[29]	ZHANG L J, WANG Y C, CUI T, et al.CaCl₂-type high-pressure phase of magnesium hydride predicted by ab initio phonon calculations[J]. Phys Rev B, 2007, 75(14):144109. doi: 10.1103/PhysRevB.75.144109
[30]	CUI S X, FENG W X, HU H Q, et al.Structural phase transitions in MgH₂ under high pressure[J]. Solid State Commun, 2008, 148(9):403-405. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=941c8a76e49dddec2d79e92804889616
[31]	ZINTL E, HARDER A.Constitution of alkaline earth hydrides[J]. Z Elektrochem, 1935, 41:33.
[32]	LEGER J M, HAINES J, ATOUF A.The high pressure behaviour of the cotunnite and post-cotunnite phases of PbCl₂ and SnCl₂[J]. J Phys Chem Solids, 1996, 57(1):7-16. http://www.sciencedirect.com/science/article/pii/0022369795000607
[33]	LEGER J M, HAINES J, ATOUF A, et al.High-pressure X-ray and neutron-diffraction studies of BaF₂:an example of a coordination number of 11 in AX₂ compounds[J]. Phys Rev B, 1995, 52(18):13247. doi: 10.1103/PhysRevB.52.13247
[34]	OLSEN J S, BURAS B, GERWARD L, et al.A new high-pressure phase and the equation of state of YbH₂[J]. Physica Scripta, 1984, 29(5):503. doi: 10.1088/0031-8949/29/5/016
[35]	LI B, LI Y W, YANG K F, et al.Raman evidence of a new high-pressure phase in calcium hydride[J]. J Phys Condens Matter, 2007, 19(22):226205. doi: 10.1088/0953-8984/19/22/226205
[36]	TSE J S, KLUG D D, DESGRENIERS S, et al.Structural phase transition in CaH₂ at high pressures[J]. Phys Rev B, 2007, 75(13):134108. doi: 10.1103/PhysRevB.75.134108
[37]	SMITH J S, DESGRENIERS S, KLUG D D, et al.High-density strontium hydride:an experimental and theoretical study[J]. Solid State Commun, 2009, 149(21):830-834. http://d.old.wanfangdata.com.cn/NSTLQK/NSTL_QKJJ0210981365/
[38]	SMITH J S, DESGRENIERS S, TSE J S, et al.High-pressure phase transition observed in barium hydride[J]. J Appl Phys, 2007, 102(4):043520. doi: 10.1063/1.2772427
[39]	KINOSHITA K, NISHIMURA M, AKAHAMA Y, et al.Pressure-induced phase transition of BaH₂:post Ni₂ in phase[J]. Solid State Commun, 2007, 141(2):69-72. doi: 10.1016/j.ssc.2006.09.045
[40]	LI Y W, LI B, CUI T, et al.High-pressure phase transformations in CaH₂[J]. J Phys Condens Matter, 2008, 20(4):045211. doi: 10.1088/0953-8984/20/04/045211
[41]	LUO W, AHUJA R.Ab initio prediction of high-pressure structural phase transition in BaH₂[J]. J Alloy Compd, 2007, 446:405-408. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=95289a20a20650e1676663509f329533
[42]	CHEN C B, TIAN F B, WANG L C, et al.New high-pressure phase of BaH₂ predicted by ab initio studies[J]. J Phys Condens Matter, 2010, 22(22):225401. doi: 10.1088/0953-8984/22/22/225401
[43]	ZHANG C, CHEN X J, ZHANG R Q, et al.Chemical trend of pressure-induced metallization in alkaline earth hydrides[J]. J Phys Chem C, 2010, 114(34):14614-14617. doi: 10.1021/jp103968c
[44]	LONIE D C, HOOPER J, ALTINTAS B, et al.Metallization of magnesium polyhydrides under pressure[J]. Phys Rev B, 2013, 87(5):054107. doi: 10.1103/PhysRevB.87.054107
[45]	ZUREK E, HOFFMANN R, ASHCROFT N W, et al.A little bit of lithium does a lot for hydrogen[J]. Proc Natl Acad Sci, 2009, 106(42):17640-17643. doi: 10.1073/pnas.0908262106
[46]	SZCZESNIAK R, DURAJSKI A P.Superconductivity well above room temperature in compressed MgH₆[J]. Front Phys, 2016, 11(6):117406. doi: 10.1007/s11467-016-0578-1
[47]	HOOPER J, ALTINTAS B, SHAMP A, et al.Polyhydrides of the alkaline earth metals:a look at the extremes under pressure[J]. J Phys Chem C, 2013, 117(6):2982-2992. doi: 10.1021/jp311571n
[48]	FENG X L, ZHANG J R, GAO G Y, et al.Compressed sodalite-like MgH₆ as a potential high-temperature superconductor[J]. RSC Adv, 2015, 5(73):59292-59296. doi: 10.1039/C5RA11459D
[49]	HOOPER J, TERPSTRA T, SHAMP A, et al.Composition and constitution of compressed strontium polyhydrides[J]. J Phys Chem C, 2014, 118(12):6433-6447. doi: 10.1021/jp4125342
[50]	PÉPIN C, LOUBEYRE P, OCCELLI F, et al.Synthesis of lithium polyhydrides above 130 GPa at 300 K[J]. Proc Natl Acad Sci, 2015, 112(25):7673-7676. doi: 10.1073/pnas.1507508112
[51]	KUNO K, MATSUOKA T, NAKAGAWA T, et al.Heating of Li in hydrogen:possible synthesis of LiH_x[J]. High Pressure Res, 2015, 35(1):16-21. doi: 10.1080/08957959.2014.999677
[52]	STRUZHKIN V V, KIM D Y, STAVROU E, et al.Synthesis of sodium polyhydrides at high pressures[J]. Nat Commun, 2016, 7:12267. doi: 10.1038/ncomms12267

Relative Articles

Supplements(0)

Cited By

Proportional views

Proportional views

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Figures(6)

Get Citation

PDF

XML

Article Metrics

Article views(15793) PDF downloads(517)

High Pressure Investigation on the Alkaline-Earth Metal Hydride

doi: 10.11858/gywlxb.2017.06.002

Abstract

References

Proportional views

Catalog

通讯作者: 陈斌, bchen63@163.com

Article Metrics

Proportional views

Related

High Pressure Investigation on the Alkaline-Earth Metal Hydride

doi: 10.11858/gywlxb.2017.06.002

Abstract

References

Proportional views

Catalog

通讯作者: 陈斌, bchen63@163.com

Article Metrics

Proportional views

Related

Export File

Citation

Format

Content