Volume 31 Issue 5
Nov 2017
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ZHANG Lei-Lei, LEI Li, HU Qi-Wei, FENG Lei-Hao, QI Lei, PU Mei-Fang. Two-Mode Behavior in Raman Spectra of Al0.86Ga0.14N Alloy under High Pressure[J]. Chinese Journal of High Pressure Physics, 2017, 31(5): 521-528. doi: 10.11858/gywlxb.2017.05.003
Citation: ZHANG Lei-Lei, LEI Li, HU Qi-Wei, FENG Lei-Hao, QI Lei, PU Mei-Fang. Two-Mode Behavior in Raman Spectra of Al0.86Ga0.14N Alloy under High Pressure[J]. Chinese Journal of High Pressure Physics, 2017, 31(5): 521-528. doi: 10.11858/gywlxb.2017.05.003

Two-Mode Behavior in Raman Spectra of Al0.86Ga0.14N Alloy under High Pressure

doi: 10.11858/gywlxb.2017.05.003
  • Received Date: 25 Feb 2017
  • Rev Recd Date: 31 Mar 2017
  • Ternary AlxGa1-xN alloy is an important semiconductor for devices in the ultraviolet and visible parts of the spectrum.So far, most studies of high Al content AlxGa1-xN alloy were mainly focused on their properties under ambient pressure and at room temperature but few on their high-pressure behavior.In this work, high Al content Al0.86Ga0.14N was investigated using the in-situ Raman scattering spectrum, and the intrinsic AlN and GaN were also studied as a comparison.The results show that the substitution of Ga by Al can be regarded as a kind of chemical pressure, and the pressure effect caused by the internal substitution can reach that caused by the external compression for GaN and the internal extension for AlN.Due to the crystalline anisotropy, the pressure effect caused by the internal substitution is more significant along the c-axis than that perpendicular to the c-axis.Moreover, the negative pressure, caused by the internal substitution, has a more significant influence on the high-pressure behavior of the AlN-like mode than that of the GaN-like mode.

     

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