ZrN-ZrB2纳米复合材料的高压制备及性能表征

陆凤国 邱利霞 丁战辉 郭星原 吕洋 赵旭东 刘晓旸

陆凤国, 邱利霞, 丁战辉, 郭星原, 吕洋, 赵旭东, 刘晓旸. ZrN-ZrB2纳米复合材料的高压制备及性能表征[J]. 高压物理学报, 2011, 25(2): 104-110 . doi: 10.11858/gywlxb.2011.02.002
引用本文: 陆凤国, 邱利霞, 丁战辉, 郭星原, 吕洋, 赵旭东, 刘晓旸. ZrN-ZrB2纳米复合材料的高压制备及性能表征[J]. 高压物理学报, 2011, 25(2): 104-110 . doi: 10.11858/gywlxb.2011.02.002
LU Feng-Guo, QIU Li-Xia, DING Zhan-Hui, GUO Xing-Yuan, Lü Yang, ZHAO Xu-Dong, LIU Xiao-Yang. High-Pressure Synthesis and Properties Characterization of ZrN-ZrB2 Nanocomposites[J]. Chinese Journal of High Pressure Physics, 2011, 25(2): 104-110 . doi: 10.11858/gywlxb.2011.02.002
Citation: LU Feng-Guo, QIU Li-Xia, DING Zhan-Hui, GUO Xing-Yuan, Lü Yang, ZHAO Xu-Dong, LIU Xiao-Yang. High-Pressure Synthesis and Properties Characterization of ZrN-ZrB2 Nanocomposites[J]. Chinese Journal of High Pressure Physics, 2011, 25(2): 104-110 . doi: 10.11858/gywlxb.2011.02.002

ZrN-ZrB2纳米复合材料的高压制备及性能表征

doi: 10.11858/gywlxb.2011.02.002
详细信息
    通讯作者:

    丁战辉

High-Pressure Synthesis and Properties Characterization of ZrN-ZrB2 Nanocomposites

More Information
    Corresponding author: DING Zhan-Hui
  • 摘要: 以金属锆粉(Zr)和六方氮化硼粉(h-BN)为原料,结合高能球磨和高温高压合成技术,制备出了ZrN-ZrB2纳米复合材料。利用X射线衍射、透射电镜和拉曼光谱等测试手段,对材料的结构和合成规律进行了研究。结果表明,高能球磨过程中只合成出了ZrNx,没有出现ZrB2,从N、B原子与Zr进行固态反应的热力学和动力学方面分析了原因。利用Zr与BN粉球磨10 h后的混料,在压力为5 GPa、温度为1 300 ℃的条件下,制备出了具有高致密度的ZrN-ZrB2纳米复合材料。其维氏显微硬度(17 GPa)、热膨胀系数(7.5710-6 ℃-1)和电阻率-温度系数(8.84610-4 ℃-1)等材料参数的测量结果表明,ZrN-ZrB2复合材料是一种集优良的力学、热学和电学性能于一体的纳米复合材料。

     

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出版历程
  • 收稿日期:  2010-06-28
  • 修回日期:  2010-09-28
  • 发布日期:  2011-04-15

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