Multi-Shock Hugoniot Equation of State of Liquid Carbon Monoxide Measured By an Optical Analysis Technique
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摘要: 结合液氮低温靶技术和光分析方法同时测量液态CO样品的第一、二、三次冲击Hugoniot状态方程,分别在19、60和71 GPa获得3个数据点。样品体积的最大压缩度达到3.5倍,比文献发表的一次冲击最大压缩度提高20%以上。体积测量值比分子流体微扰变分理论的计算结果偏低20%以上,体积发生明显软化现象归因于CO分解反应所致。详述了多次冲击过程的光分析测量方法,该方法应用于其它分子流体可将其物态方程的实验数据点延伸到更高压力和更宽的压缩范围。
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关键词:
- 光分析技术 /
- 低温靶技术 /
- 液态CO /
- 多次冲击 /
- Hugoniot状态方程
Abstract: The cryogenic target technique and an optical analysis technique are combined to measure multi-shock Hugoniot equations of state of liquid carbon monoxide. The first, second, and third shock pressures are respectively 19 GPa, 60 GPa, and 71 GPa. The maximum compression ratio of volume reaches three point five and twenty percent higher than that of ever reported one. The measured results for specific volume are nearly twenty percent less than the predicted ones by molecular fluid theory, which is attributed to the molecular dissociation reactions of carbon monoxide under shock compressions. The detail of the measurement technique and calculation method are described, and such a scheme can be applied to other molecular fluids to achieve higher pressures and larger compression ratios. -
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