立方氮化硅及其冲击波合成

贺红亮

doi:10.11858/gywlxb.2007.01.001

立方氮化硅及其冲击波合成

doi: 10.11858/gywlxb.2007.01.001

贺红亮

中国工程物理研究院流体物理研究所冲击波物理与爆轰物理实验室，四川绵阳 621900

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贺红亮

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出版历程
- 收稿日期: 2006-07-11
- 修回日期: 2007-01-03
- 发布日期: 2007-03-05

Cubic Silicon Nitride and Its Synthesis by Shock Wave Compression

HE Hong-Liang

Laboratory for Shock Wave and Detonation Physics Research, Institute of Fluid Physics, CAEP, Mianyang 621900, China

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Corresponding author: HE Hong-Liang

摘要

摘要: 立方氮化硅是高温高压研究近期合成得到的一种新物相，与已经在工业上普遍使用的氮化硅的两种六方物相（相和相）相比，新物相的密度增加了26%，预期是一种新型功能材料。简要综述了立方氮化硅的研究进展和存在的问题，讨论了立方氮化硅的人工合成和相关物性研究、Ⅳ(A)族氮化物（Ge3N4、Sn3N4、C3N4）的高密度物相研究，以及后尖晶石相氮化物的实验和理论探索等问题。介绍了作者最近利用炸药爆轰加载技术开展的冲击波合成实验结果，以相氮化硅为冲击压缩前驱体，实现了在单次冲击波压缩实验中合成出了克量级立方氮化硅粉体，为进一步开展立方氮化硅的性能研究奠定了基础。
- 立方氮化硅 /
- 冲击波压缩 /
- 合成
Abstract: Cubic silicon nitride is a new polymorphous of Si3N4 synthesized under high pressure and high temperature. Compared to the two known hexagonal phases of and , the new phase is about 26% denser in density, and it is predicted to be a new multi-functional ceramic. The achievement and related concern of the cubic silicon nitride have been reviewed in this paper, including the progress in artificial synthesis, the study on its physical property, the synthesis of other Ⅳ(A) group denser nitrides (Ge3N4, Sn3N4, C3N4), and the explore of the possible post-spinel phase of nitride. By using a flyer impact technique with explosive detonation, we recently have synthesized the cubic silicon nitride from the precursor of -Si3N4, and the mass production of the cubic phase has reached about 2 grams in each run of the shock wave compression test, which provides an economic way for further investigation of its potential performance in industriy.
- cubic silicon nitride /
- shock compression /
- synthesis

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参考文献(38)

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