Graphitization Process of Diamond Surfaces During the Sintering of Diamond-Cobalt System under Pressure and Temperature
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摘要: 通过3组模拟实验,考察了低压高温下金刚石表面石墨化条件和超高压高温条件下金刚石表面石墨化过程,发现在钴-碳共晶点以下、超高压高温烧结样品WC-Co基体附近区域金刚石表面已发生石墨化,XRD测试结果表明,超高压高温烧结过程中金刚石表面经历了石墨化初期、高峰期和抑制期三个阶段。Abstract: The conditions of graphitization on diamond surface under high temperature and the graphitization process of diamond under high pressure and temperature were investigated experimentally. The graphitization on the surface of diamond near WC-Co substrate was discovered in samples sintered at the temperature below the cobalt-diamond eutectic point. The XRD testing results show that the diamond powders experienced three graphitization stages during the sintering process under high pressure and high temperature, they are, graphitization accelerated stage, climax stage and restrained stage.
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Key words:
- diamond /
- graphitization /
- sintering
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Akaishi M, Handa H, et al. The Sintering Behavior of Diamond-Cobalt System under High Pressure and Temperature [J]. J Mater Sci, 1982, 17: 193-195. 张兴栋, 彭应聪, 邱淑蓁, 等. 多晶金刚石烧结中晶粒表面石墨化的实验研究 [J]. 高压物理学报, 1989, 13(2): 125-131. 冯时雍, 邱淑蓁, 李伯勋. 多晶烧结过程中金刚石表面石墨化研究 [J]. 人工晶体学报, 1987, 16(3): 238- 242. 彳七乇烧结(;: 関研究[R]. 日本无机材质研究所报告书第39号, 1984. 3. 福长修. 新素材开发のフロンテイア, 1985: 30. [6 ] Lee Minyoung. US Pat: 4, 168, 957. Darxow K A, Sprakers N Y. US Pat: 3, 306, 270. 李伯勋, 张兴栋, 邱淑蓁, 等. 石墨化在金刚石多晶髙压烧结中的作用 [J]. 四川大学学报, 1986, 2: 63-71. Field J E. The Properties of Diamond [M]. London: Academic Press, 1979. 408. 奈基奇Ю B, 科列斯尼钦Г A. 熔融金属与金刚石和石墨表面的相互作用 [J]. 人工晶体, 1978, 11(1): 71-79. 傅慧芳, 朱成明. 静态超高压容器中温度、压力等参数的测试 [J]. 物理, 1979, 9(3): 193. Strong H M, Tuft R E. Research and Development [R]. New York, 1974. 邓福铭. PDC超硬复合材料髙压合成规律及其机理研究 [D]. 长沙: 中南工业大学, 1999: 95. Hong S M, Minoru Akaishi, et al. Journal of Materials Science, 1988, 23: 3821-3826. 李光照, 冯楚德, 薛志麟. 人造金刚石的溶液生长机制 [J]. 硅酸盐学报, 1984, 12(1): 91-95.
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