Raman Scattering of Grossular-Andradite Solid Solution

WANG Yichuan

doi:10.11858/gywlxb.20200512

Volume 34 Issue 4

Jul 2020

Turn off MathJax

Article Contents

Chinese Journal of High Pressure Physics > 2020 > 34(4): 040101.

WANG Yichuan. Raman Scattering of Grossular-Andradite Solid Solution[J]. Chinese Journal of High Pressure Physics, 2020, 34(4): 040101. doi: 10.11858/gywlxb.20200512

Citation:

WANG Yichuan. Raman Scattering of Grossular-Andradite Solid Solution[J]. Chinese Journal of High Pressure Physics, 2020, 34(4): 040101. doi: 10.11858/gywlxb.20200512

WANG Yichuan. Raman Scattering of Grossular-Andradite Solid Solution[J]. Chinese Journal of High Pressure Physics, 2020, 34(4): 040101. doi: 10.11858/gywlxb.20200512

Citation:

WANG Yichuan. Raman Scattering of Grossular-Andradite Solid Solution[J]. Chinese Journal of High Pressure Physics, 2020, 34(4): 040101. doi: 10.11858/gywlxb.20200512

PDF( 3397 KB)

Raman Scattering of Grossular-Andradite Solid Solution

doi: 10.11858/gywlxb.20200512

WANG Yichuan^{1, 2
,}

1.
School of Earth and Space Sciences, Peking University, Beijing 100871, China
2.
Key Laboratory of Orogenic Belts and Crustal Evolution, MOE, Peking University, Beijing 100871, China

Received Date: 20 Feb 2020
Rev Recd Date: 08 Mar 2020

Abstract

Abstract

The effects of Al³⁺-Fe³⁺ substitution on 10 synthesized garnet samples along the grossular-andradite binary were investigated using Raman spectroscopy. Twenty and nineteen peaks were observed in non-polarized Raman spectra for grossular and andradite end-members, respectively. The frequencies of most peaks were changed almost linearly with the composition. Two-mode behavior was not observed in this study. Differing from previous reports on other garnet solid solutions, the medium frequency modes, which are assigned to internal bending vibrations, have the largest average rate of change with the composition, which may be related to structural connectivity and coupled vibrations. Due to the reduction of symmetry, extra peaks appear in the Raman spectra of garnets with intermediate compositions. Peak broadening in intermediate compositions was also observed, which is related to disordering and distortion. One-parameter Margules equation was used to describe the full width at half maximum of peaks, and a relationship with enthalpy of mixing was proposed.
- grossular-andradite,
- Raman spectroscopy,
- bending vibration,
- extra peak,
- enthalpy of mixing

FullText(HTML)

References(34)

References

[1]	GREW E S, LOCOCK A J, MILLS S J, et al. Nomenclature of the garnet supergroup [J]. American Mineralogist, 2013, 98(4): 785–810. doi: 10.2138/am.2013.4201
[2]	HAZEN R M, DOWNS R T, CONRAD P G, et al. Comparative compressibilities of majorite-type garnets [J]. Physics and Chemistry of Minerals, 1994, 21(5): 344–349. doi: 10.1007/BF00202099
[3]	CONRAD P G, ZHA C S, MAO H K, et al. The high-pressure, single-crystal elasticity of pyrope, grossular, and andradite [J]. American Mineralogist, 1999, 84(3): 374–383. doi: 10.2138/am-1999-0321
[4]	DU W, CLARK S M, WALKER D. Thermo-compression of pyrope-grossular garnet solid solutions: non-linear compositional dependence [J]. American Mineralogist, 2015, 100(1): 215–222. doi: 10.2138/am-2015-4752
[5]	BLUNDY J, WOOD B. Prediction of crystal-melt partition coefficients from elastic moduli [J]. Nature, 1994, 372(6505): 452–454. doi: 10.1038/372452a0
[6]	SUN C G, LIANG Y. The importance of crystal chemistry on REE partitioning between mantle minerals (garnet, clinopyroxene, orthopyroxene, and olivine) and basaltic melts [J]. Chemical Geology, 2013, 358: 23–36. doi: 10.1016/j.chemgeo.2013.08.045
[7]	GANGULY J, CHENG W J, O’NEILL H S C. Syntheses, volume, and structural changes of garnets in the pyrope-grossular join: implications for stability and mixing properties [J]. American Mineralogist, 1993, 78(5/6): 583–593.
[8]	GEIGER C A. Silicate garnet: a micro to macroscopic (re)view [J]. American Mineralogist, 2008, 93(2/3): 360–372. doi: 10.2138/am.2008.2588
[9]	GEIGER C A, FEENSTRA A. Molar volumes of mixing of almandine-pyrope and almandine-spessartine garnets and the crystal chemistry and thermodynamic-mixing properties of the aluminosilicate garnets [J]. American Mineralogist, 1997, 82(5/6): 571–581. doi: 10.2138/am-1997-5-617
[10]	NEWTON R C, CHARLU T V, KLEPPA O J. Thermochemistry of high pressure garnets and clinopyroxenes in the system CaO-MgO-Al₂O₃-SiO₂ [J]. Geochimica et Cosmochimica Acta, 1977, 41(3): 369–377. doi: 10.1016/0016-7037(77)90264-2
[11]	UNGARETTI L, LEONA M, MERLI M, et al. Non-ideal solid-solution in garnet: crystal-structure evidence and modelling [J]. European Journal of Mineralogy, 1995, 7(6): 1299–1312. doi: 10.1127/ejm/7/6/1299
[12]	BOFFA BALLARAN T, CARPENTER M A, GEIGER C A, et al. Local structural heterogeneity in garnet solid solutions [J]. Physics and Chemistry of Minerals, 1999, 26(7): 554–569. doi: 10.1007/s002690050219
[13]	DU W, HAN B F, CLARK S M, et al. Raman spectroscopic study of synthetic pyrope-grossular garnets: structural implications [J]. Physics and Chemistry of Minerals, 2018, 45(2): 197–209. doi: 10.1007/s00269-017-0908-z
[14]	KOLESOV B A, GEIGER C A. Raman spectra of silicate garnets [J]. Physics and Chemistry of Minerals, 1998, 25(2): 142–151. doi: 10.1007/s002690050097
[15]	MCALOON B P, HOFMEISTER A M. Single-crystal IR spectroscopy of grossular-andradite garnets [J]. American Mineralogist, 1995, 80(11/12): 1145–1156. doi: 10.2138/am-1995-11-1205
[16]	HOFMEISTER A M, FAGAN T J, CAMPBELL K M, et al. Single-crystal IR spectroscopy of pyrope-almandine garnets with minor amounts of Mn and Ca [J]. American Mineralogist, 1996, 81(3/4): 418–428. doi: 10.2138/am-1996-3-416
[17]	HOFMEISTER A M, CHOPELAS A. Vibrational spectroscopy of end-member silicate garnets [J]. Physics and Chemistry of Minerals, 1991, 17(6): 503–526. doi: 10.1007/BF00202230
[18]	SHANNON R D. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides [J]. Acta Crystallographica Section A, 1976, 32(5): 751–767. doi: 10.1107/S0567739476001551
[19]	BOFFA BALLARAN T, WOODLAND A B. Local structure of ferric iron-bearing garnets deduced by IR-spectroscopy [J]. Chemical Geology, 2006, 225(3/4): 360–372. doi: 10.1016/j.chemgeo.2005.08.028
[20]	WANG Y C, SUN Q, DUAN D F, et al. The study of crystal structure on grossular-andradite solid solution [J]. Minerals, 2019, 9(11): 691. doi: 10.3390/min9110691
[21]	LIU X, CHEN J L, TANG J J, et al. A large volume cubic press with a pressure-generating capability up to about 10 GPa [J]. High Pressure Research, 2012, 32(2): 239–254. doi: 10.1080/08957959.2012.657634
[22]	GILLET P, FIQUET G, MALEZIEUX J M, et al. High-pressure and high-temperature Raman spectroscopy of end-member garnets: pyrope, grossular and andradite [J]. European Journal of Mineralogy, 1992, 4(4): 651–664. doi: 10.1127/ejm/4/4/0651
[23]	MOORE R K, WHITE W B, LONG T V. Vibrational spectra of the common silicates: I. the garnets [J]. American Mineralogist, 1971, 56(1/2): 54–71.
[24]	PASCALE F, CATTI M, DAMIN A, et al. Vibration frequencies of Ca₃Fe₂Si₃O₁₂ andradite: an ab initio study with the CRYSTAL code [J]. Journal of Physical Chemistry B, 2005, 109(39): 18522–18527. doi: 10.1021/jp052991e
[25]	PASCALE F, ZICOVICH-WILSON C M, ORLANDO R, et al. Vibration frequencies of Mg₃Al₂Si₃O₁₂pyrope. an ab initio study with the CRYSTAL code [J]. The Journal of Physical Chemistry B, 2005, 109(13): 6446–6152. doi: 10.1021/jp050316z
[26]	BORN L, ZEMANN J. Abstandsberechnungen und gitterenergetische Berechnungenan Granaten [J]. Beiträgezur Mineralogie und Petrographie, 1964, 10(1): 2–23. doi: 10.1007/BF01192531
[27]	WOODLAND A B, ROSS II C R. A crystallographic and mössbauer spectroscopy study of ${ {\rm{Fe}}_3^{2 + } }$ Al₂Si₃O₁₂- ${{\rm{Fe}}_3^{2 + }{\rm{Fe}}_2^{3 + }}$ Si₃O₁₂, (Almandine-"Skiagite") and Ca₃ ${{\rm{Fe}}_3^{2 + }}$ Si₃O₁₂- ${{\rm{Fe}}_3^{2 + }{\rm{Fe}}_2^{3 + }}$ Si₃O₁₂ (Andradite-"Skiagite") garnet solid solutions [J]. Physics and Chemistry of Minerals, 1994, 21(3): 117–132. doi: 10.1007/BF00203142
[28]	ZIMAN J M. Models of disorder: the theoretical physics of homogeneously disordered systems [M]. Cambridge: Cambridge University Press, 1979.
[29]	DE LA PIERRE M, NOEL Y, MUSTAPHA S, et al. The infrared vibrational spectrum of andradite-grossular solid solutions: a quantum mechanical simulation [J]. American Mineralogist, 2013, 98(5/6): 966–976. doi: 10.2138/am.2013.4156
[30]	DEMPSEY M J. Evidence for structural changes in garnet caused by calcium substitution [J]. Contributions to Mineralogy and Petrology, 1980, 71(3): 281–282. doi: 10.1007/BF00371669
[31]	FEI X H, ZHANG Z C, CHENG Z G, et al. Factors controlling the crystal morphology and chemistry of garnet in skarn deposits: a case study from the Cuihongshan polymetallic deposit, Lesser Xing’an Range, NE China [J]. American Mineralogist, 2019, 104(10): 1455–1468. doi: 10.2138/am-2019-6968
[32]	GASPAR M, KNAACK C, MEINERT L D, et al. REE in skarn systems: a LA-ICP-MS study of garnets from the Crown Jewel gold deposit [J]. Geochimica et Cosmochimica Acta, 2008, 72(1): 185–205. doi: 10.1016/j.gca.2007.09.033
[33]	XU J, CIOBANU C L, COOK N J, et al. Skarn formation and trace elements in garnet and associated minerals from Zhibula copper deposit, Gangdese Belt, southern Tibet [J]. Lithos, 2016, 262: 213–231. doi: 10.1016/j.lithos.2016.07.010
[34]	BECKER U, POLLOK K. Molecular simulations of interfacial and thermodynamic mixing properties of grossular-andradite garnets [J]. Physics and Chemistry of Minerals, 2002, 29(1): 52–64. doi: 10.1007/s002690100211

Relative Articles

Supplements(0)

Cited By

Proportional views

Proportional views

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Figures(5) / Tables(1)

Get Citation

PDF

XML

Article Metrics

Article views(7803) PDF downloads(41)

Raman Scattering of Grossular-Andradite Solid Solution

doi: 10.11858/gywlxb.20200512

Abstract

References

Proportional views

Catalog

通讯作者: 陈斌, bchen63@163.com

Article Metrics

Proportional views

Related

Raman Scattering of Grossular-Andradite Solid Solution

doi: 10.11858/gywlxb.20200512

Abstract

References

Proportional views

Catalog

通讯作者: 陈斌, bchen63@163.com

Article Metrics

Proportional views

Related

Export File

Citation

Format

Content