六角相硼碳氮化合物的合成研究

李雪飞; 张剑; 沈龙海; 杨大鹏; 崔启良; 邹广田

doi:10.11858/gywlxb.2007.03.003

六角相硼碳氮化合物的合成研究

doi: 10.11858/gywlxb.2007.03.003

1.
吉林大学超硬材料国家重点实验室，吉林长春 130012；
2.
吉林师范大学，吉林四平 136000；
3.
沈阳理工大学，辽宁沈阳 110168

详细信息

通讯作者:
张剑

计量
- 文章访问数: 13941
- HTML全文浏览量: 835
- PDF下载量: 993
出版历程
- 收稿日期: 2006-10-09
- 修回日期: 2007-03-17
- 发布日期: 2007-09-05

Synthesis and Characterization of h-BCN Nanocrystallite under High-Pressure and High-Temperature

1.
National Laboratory of Superhard Materials Jilin University, Changchun 130012, China;
2.
Jilin Normal University, Siping 136000, China;
3.
Shenyang Ligong University, Shenyang 110168, China

More Information

Corresponding author: ZHANG Jian

摘要

摘要: 以三聚氰胺和氧化硼为原料，利用真空热处理和高温高压技术，对BCN化合物的形成及结构进行了研究。在真空条件下，原料经1 100 K热处理得到非晶BCN的前驱物，将前驱物在5.0 GPa、1 500 K条件下高温高压热处理30 min，合成出了单相的六角BCN晶体。采用Materials Studio软件的Reflex模块对样品的X射线衍射图谱进行分析，结果表明，得到的样品为纯的六角相，晶格常数为a=0.250 5 nm，c=0.665 9 nm。对样品进行了透射电镜（TEM）分析，得到了样品的形貌和电子衍射，同样证实了样品为六角BCN晶体，晶粒尺寸约200 nm。对样品进行了XPS表征，确定了样品中存在CC、CN、CB、NB键，表明B、C、N三元素之间达到了原子级化合，样品的组分含量通过EDX进行标定。
- 高温高压 /
- h-BCN /
- 前驱物
Abstract: h-BCN compounds were synthesized with C3H6N6 and B2O3 as raw materials, combined with heat treatment, high pressure and high temperature. An amorphous BCN precursor was prepared at 1 100 K under vacuum. Annealed for 30 min, at 1 500 K under 5.0 GPa, the amorphous BCN precursor crystallizes into hexagonal BCN compound with lattice constants of a=0.250 5 nm, c=0.665 9 nm determined by using the reflex module combined in the Materials Studio program analysis. The shape and SAD of sample also approved that the sample was h-BCN crystal by TEM analysis. The grain size about was 200 nm. XPS analysis was applied for the sample. The results confirmed bending energy of CC, CN, CB, NB. It indicated atom level chemical combination of BCN. The composition and content of the sample were analyzed by EDX.
- high temperature and high pressure /
- h-BCN /
- precursor

HTML全文

参考文献(14)

Liu A Y, Wentzcovitch R M, Cohen M L. Atomic Arrangement and Electronic Structure of BC2N [J]. Phys Rev B, 1989, 39: 1760-1765.

Kosolapova T Y, Makarenko G N, Serebryakova T I, et al. Boron Carbonitride－(Ⅰ) Conditions for Preparing Boron Carbonitride [J]. Poroshk Metall, 1971, 1: 25.

Andreev Y G, LundestrEm T. Hihg-Temperature Synthesis and Investigation of Hexagonal Boron Carbonitride [J]. J Alloys Compounds, 1994, 210: 311.

Popov C, Saito K, Ivanov B, et al. Chemical Vapor Deposition of BC2N Films and Their Laser-Induced Etching with SF6 [J]. Thin Solid Films, 1998, 312: 99-105.

Chen W J, Hua Zh, Yao B, et al. The Preparation and Conductivity of Amorphous BCN [J]. Acta Metallurgica Sinica, 1999, 5(5): 469-472. (in Chinese)

陈万金, 华中, 姚斌, 等. 非晶BCN 的制备及其导电性 [J]. 金属学报, 1999, 35(5): 469 -472.

Yao B, Ye S, Wu R Zh, et al. Formation and Electric Properties of B2C2N Compound [J]. Chinese Journal of High Pressure Physics, 1999, 13(Suppl): 191-195. (in Chinese)

姚斌, 叶森, 吴瑞芝, 等. B2C2N新相及其导电性 [J]. 高压物理学报, 1999, 13(增刊): 191-195.

He J L, Tian Y J, Yu D L, et al. Structure Characterization of High Pressure Synthesized BCN Compounds [J]. Journal of The Chinese Ceramic Society, 2002, 30: 51. (in Chinese)

何巨龙, 田永君, 于栋利, 等高压合成BCN化合物的结构表征 [J]. 硅酸盐学报, 2002, 30: 51.

Bai S Zh, Yao B, Su W H. Synthesis, Characterization and Properties of B0. 44C0. 27N0. 29 Compounds [J]. Acta Physica Sinica, 2005, 54: 4627-4632. (in Chinese)

白锁柱, 姚斌, 苏文辉. B0. 44C0. 27N0. 29化合物的合成、表征和性能 [J]. 物理学报, 2005, 54: 4627-4632.

Watannbe M O, Itoh S, Mizushima K, et al. Bonding Characterization of BC2N Thin Films [J]. Appl Phys Lett, 1996, 68: 2962-2964.

Guo Q X, Xie Y, Wang X J, et al. Characterization of Well-Crystallized Graphitic Carbon Nitride Nanocrystallites via a Benzene-Thermal Route at Low Temperatures [J]. Chem Phys Lett, 2003, 380: 84-87.

施引文献

资源附件(0)

访问统计